Graphene oxide modified with carboxymethyl cellulose for high adsorption capacities towards Nd(III) and Ce(III) from aqueous solutions

This work addresses a simple method to functionalize graphene oxide with sodium carboxymethyl cellulose using tetraethyl orthosilicate as a linker for rapid and significant removal of Nd(III) and Ce(III) from aqueous solutions. The prepared composite (GO-CMC) was characterized by different techniques to confirm the modification and adsorption process. The sorption performance of the GO-CMC was evaluated using Nd(III) and Ce(III) as absorbent materials. The experimental results demonstrated that the sorption process was excellently fitted by the pseudo-second-order kinetic model. The adsorption results were also analyzed by different isotherm models. According to the Langmuir isotherm model, the experimental sorption capacities at pH 3.0 was 661.21 and 436.55 mg/g for Nd(III) and Ce(III), respectively. The thermodynamic results indicated that the sorption process of the two examined metal ions was endothermic and spontaneous. The regenerated GO-CMC composite has a similar removal percentage to the original composite. These results confirmed that the prepared composite (GO-CMC) could be used as an effective adsorbent for Nd(III) and Ce(III) from certain multielement solutions.

Automated summary

This research presents a simple method to functionalize graphene oxide with sodium carboxymethyl cellulose using tetraethyl orthosilicate as a linker for the rapid and significant removal of Nd(III) and Ce(III) from aqueous solutions. The prepared composite (GO-CMC) demonstrates excellent adsorption performance, fitting well with pseudo-second-order kinetic model and Langmuir isotherm model.