Journal
CARBON
Volume 199, Issue -, Pages 132-140Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2022.07.043
Keywords
DLC; NEXAFS; Amorphous carbon; ATP
Funding
- Welch Foundation [F-2002-20190330]
- National Science Foundation Faculty Early Career Development Program [2042304]
- Taiho Kogyo Tribology Research Foundation [20A03]
- 2018 Ralph E. Powe Junior Faculty Enhancement Award - Oak Ridge Associated Univer- sities (ORAU)
- Walker Department of Mechanical Engineering
- Texas Materials Institute at the University of Texas at Austin
- Div Of Civil, Mechanical, & Manufact Inn
- Directorate For Engineering [2042304] Funding Source: National Science Foundation
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Silicon-containing diamond-like carbon (DLC) coatings exhibit excellent tribological properties and resistance to biomolecule surface adsorption. This study provides insights into the influence of silicon on the structural and mechanical properties of DLC, showing a decrease in friction and an increase in surface hydroxyl groups with increasing silicon content.
Silicon-containing diamond-like carbon (DLC) is a class of thin-film materials with excellent mechanical prop-erties, high thermal stability, and good tribological performance over a wide range of environmental conditions. While non-alloyed/non-doped DLCs also exhibit good biocompatibility and bioinertness, our understanding of the effect of silicon in DLCs on biomolecules/DLC interactions is still elusive. Here, we evaluated the structural, mechanical, and tribological properties of Si-containing DLC coatings with silicon content fraction of 11% and 16%. Tribological tests, performed by sliding a stainless steel pin on the coatings in water, indicated a low friction response (steady-state coefficient of friction < 0.11), while quartz crystal microbalance experiments indicated no adsorption of a model biomolecule, namely adenosine triphosphate (ATP), on Si-containing DLCs. Near-edge X-ray absorption fine structure spectromicroscopy analyses performed after tribological experiments provided evidence for an increase in the fraction of silanol surface terminal groups formed in the worn region upon sliding in water without any significant sp3-to-sp2 rehybridization of carbon atoms. The fraction of surface hydroxyl groups in the worn region increases with the silicon content in Si-containing DLC, which leads to a decrease in friction. This tribologically-induced change in surface termination did not lead to the adsorption of ATP upon incubation of tribotested samples in ATP solutions for several hours. These findings open the path for the use of Si-containing DLC in applications requiring good tribological properties in aqueous solution and an excellent resistance to biomolecule surface adsorption that is maintained even after tribologically-induced var-iations in surface termination.
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