Journal
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Volume 95, Issue 10, Pages 1501-1505Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20220171
Keywords
C(sp(3))-H allylation; C(sp(3))-H alkynylation; C(sp(3))-H imination
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Funding
- Ministry of Science and Technology, Taiwan [MOST108-2636-M-009-003, MOST-108-2113-M-009-007]
- Center for Emergent Functional Matter Science at NYCU [111W20253]
- JSPS [19H02722]
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Photocatalytic C(sp(3))-H allylation, alkynylation, and imination using unsaturated benzenesulfonyl compounds were investigated with decatungstate W10O324- as the photocatalyst. In all these reactions, selective cleavage of C(sp(3))-H bonds was achieved and combined with the radical addition/ss-scission sequence.
Photocatalytic C(sp(3))-H allylation, alkynylation, and imination using unsaturated benzenesulfonyl compounds were studied using decatungstate anion, W10O324-, as photocatalyst. In all these reactions, site-selective C(sp(3))-H bond cleavage was successfully combined with the radical addition/ss-scission sequence.
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