Catalytic gasification of indole in supercritical water with non-noble bimetallic catalysts

Indole is commonly reported as a N-containing heterocyclic compounds in biomass supercritical water gasifi-cation (SCWG), and is difficult to be degraded to small molecule substances. In this work, Ni/AC, Ni-Cu/AC, Ni-Co/AC, Ni-Ce/AC were prepared and tested for catalytic SCWG of indole. The results showed that Ni-Cu/AC had the highest activity for converting indole and producing gases, leading to the highest hydrogen gasification efficiency (135.1%) and carbon gasification efficiency (33.1%). During the catalytic SCWG of indole, the addition of auxiliary metal Cu in multi-component catalyst showed synergistic effects by changing reaction pathways and reaction rates. It significantly promoted water-gas shift and steam reforming reactions, so forming the highest H2 yield of 2.62 mol mol-1. Furthermore, large specific surface, Ni reduction and high catalyst stability point to potential advantages of the Ni-Cu/AC catalyst for catalytic SCWG of recalcitrant N-containing compounds.

Automated summary

This study prepared different combinations of catalysts and tested their catalytic SCWG effects on indole. The results showed that Ni-Cu/AC catalyst with the addition of auxiliary metal Cu exhibited the highest catalytic activity and gasification efficiency, which resulted from synergistic effects by changing reaction pathways and rates. Additionally, the Ni-Cu/AC catalyst showed potential advantages in terms of large specific surface, Ni reduction, and high catalyst stability for catalytic SCWG of recalcitrant N-containing compounds.