4.7 Article

Hydrophobic Biodegradable Hyperbranched Copolymers with Excellent Marine Diatom Resistance

Journal

BIOMACROMOLECULES
Volume -, Issue -, Pages -

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.biomac.2c00779

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The study introduces a hydrophobic surface-fragmenting coating made of degradable hyper-branched polymers, which exhibits superior resistance to diatom adhesion and has self-renewable surfaces. The coating also shows excellent antibacterial adhesion properties and environmental friendliness. Therefore, it has great potential in antifouling coating applications.
As the utilization of degradable polymer coatings increased, the accompanying trade-off between good degradability and high-efficiency antidiatom adhesion due to their hydrophobic nature remains unresolved. The study presents a new hydrophobic surface-fragmenting coating consisting of degradable hyper-branched polymers (hereafter denoted as h-LLA(x)) synthesized by reversible complexation-mediated copolymerization with isobornyl acrylate (IBOA) and divinyl-functional oligomeric poly(L-lactide) (OLLA-V-2), both derived from biomass, that exhibited superior resistance (similar to 0 cell mm(-2)) to marine diatom Navicula incerta (N. incerta) attachment with higher OLLA content. The combined impact of the microscale hollow semisphere micelles that self-assembled degradable hyperbranched copolymers and hydrolysis-driven self-renewable surfaces following immersion in seawater may account for the remarkable resistance of h-LLA(x) coatings against N. incerta. Detailed investigations were conducted across multiple perspectives, from hydrolytic degradation to broad-spectrum antibacterial attachment to ecotoxicity assessment. The excellent features of high resistance to marine diatoms and bacterial attachment, degradability, and environmental friendliness make the as-prepared h-LLA(x) coatings widely sought after for antifouling coating applications.

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