Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 18, Issue -, Pages 1055-1061Publisher
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.18.107
Keywords
enone; hydrogenation; iridium; palladium; PEM reactor
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Funding
- JST CREST, Japan [JP65R1204400]
- JSPS KAKENHI [JP19K05477, JP19K05478, JP22H02122]
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This paper describes the electrochemical hydrogenation of enones using a proton-exchange membrane reactor. The reduction of enones proceeded smoothly under mild conditions to produce ketones or alcohols. The reaction showed chemoselectivity with the use of different cathode catalysts (Pd/C or Ir/C).
Electrochemical hydrogenation of enones using a proton-exchange membrane reactor is described. The reduction of enones proceeded smoothly under mild conditions to afford ketones or alcohols. The reaction occurred chemoselectively with the use of different cathode catalysts (Pd/C or Ir/C).
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