4.5 Article

Electrochemical hydrogenation of enones using a proton- exchange membrane reactor: selectivity and utility

Journal

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 18, Issue -, Pages 1055-1061

Publisher

BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.18.107

Keywords

enone; hydrogenation; iridium; palladium; PEM reactor

Funding

  1. JST CREST, Japan [JP65R1204400]
  2. JSPS KAKENHI [JP19K05477, JP19K05478, JP22H02122]

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This paper describes the electrochemical hydrogenation of enones using a proton-exchange membrane reactor. The reduction of enones proceeded smoothly under mild conditions to produce ketones or alcohols. The reaction showed chemoselectivity with the use of different cathode catalysts (Pd/C or Ir/C).
Electrochemical hydrogenation of enones using a proton-exchange membrane reactor is described. The reduction of enones proceeded smoothly under mild conditions to afford ketones or alcohols. The reaction occurred chemoselectively with the use of different cathode catalysts (Pd/C or Ir/C).

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