Journal
APPLIED PHYSICS EXPRESS
Volume 15, Issue 10, Pages -Publisher
IOP Publishing Ltd
DOI: 10.35848/1882-0786/ac93e5
Keywords
chemical vapor deposition; hexagonal boron nitride; edge-controlled
Categories
Funding
- National Natural Science Foundation of China [51902285, 52072336]
- Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering [2022SZ-FR001]
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In this study, the role of the edge during the growth of hexagonal boron nitride (hBN) by chemical vapor deposition (CVD) was investigated. The researchers demonstrated two types of hydrogen-induced edge evolution of single-crystal hBN domains over time on liquid Cu via CVD. The results were well explained by the kinetic Wulff construction theory and provide insights into the production of large-scale single-crystalline hBN.
Understanding the role of the edge during the growth of hexagonal boron nitride (hBN) by chemical vapor deposition (CVD) is essential for its controllable synthesis and applications. We demonstrated two kinds of hydrogen-induced edge evolution of single-crystal hBN domains over time on liquid Cu via CVD. The morphology and edge evolution of the hBN domains in growth were well explained by the kinetic Wulff construction theory. This work provides a detailed understanding of the role of the edge during the growth progress of hBN, which will be helpful for the production of wafer-scale single-crystalline hBN.
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