4.6 Article

Fabrication and properties of super-hydrophobic microstructures on magnesium alloys by laser-chemical etching

Journal

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s00339-022-05998-9

Keywords

Magnesium alloy; Laser etching; CuCl2 solution etching; Super-hydrophobicity; Corrosion resistance

Funding

  1. Jiangsu Overseas Visiting Scholar Program for University Prominent Young&Middle-aged Teachers and Presidents (2017)
  2. Qinglan Project Foundation of Jiangsu Province (2016)
  3. Technological Production Translation of Jiangsu Province [BA2015129]

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This study fabricated super-hydrophobic microstructures on the surface of AZ91 magnesium alloy using laser-chemical composite etching and stearic acid modification. The resulting structure demonstrated excellent super-hydrophobicity and low adhesion, effectively preventing water droplets and contaminants from adhering to the surface.
The super-hydrophobic microstructures were fabricated on the surface of AZ91 magnesium alloy by laser-chemical composite etching and stearic acid modification. The results show that the special concave and convex structures and grooves arranged in micro-scale were formed on the surface of specimens after laser etching. The sharpened grid grooves and rice-husk-like structures were constructed on the surface after CuCl2 solution etching. After laser-chemical composite etching and stearic acid modification, the surface presents good super-hydrophobicity and low adhesion with the water contact angle of 158.4 degrees. Moreover, water droplets can easily roll off the surface of super-hydrophobic samples and carry contaminants along the rolling path. The corrosion resistance test shows that the magnesium alloy with super-hydrophobic structure has higher self-corrosion potential, lower self-corrosion current density and significantly higher impedance, indicating that it has good corrosion resistance.

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