Journal
APPLIED CLAY SCIENCE
Volume 226, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.clay.2022.106579
Keywords
Montmorillonite; Radionuclides; Interlayer exchange; Dynamic process; Molecular mechanism
Funding
- Natural Science Foundation of China [41877126]
- China Postdoctoral Science Foundation [2021M692652]
- Northwest A & F University (NWAFU)
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This study elucidates the dynamic exchange processes, microscopic structures, aqueous species distributions, and diffusion properties of radioactive nuclides onto clay minerals using molecular modeling technique. The study provides insights into the exchange characteristics and mechanisms, as well as the factors affecting the exchange processes.
The reliability of long-term safety assessments of radioactive waste repositories can be improved by a molecular level knowledge of the geochemical processes onto clay minerals, such as montmorillonite. However, a mechanistic understanding of the dynamic exchange processes of radionuclides into the interlayer region of montmorillonite is still unclear. Using molecular modeling technique, we elucidate the dynamic exchange characteristics, microscopic structures, aqueous species distributions, and diffusion properties of the exchange of radioactive nuclides. The exchange ratios are in the order of Cs+ asymptotic to Rb+ asymptotic to UO22+ > > Ba2+ asymptotic to Sr2+ > > Eu3+, and Cl- can enter the interlayer space by associating with nuclides. Formation of aqueous CO32--UO22+ clusters largely reduces exchange amount. Unlike CO32-, other anions (Cl-, I-, SO42-, and TcO4-) show relatively weaker binding ability with UO22+. We find that multivalent cations prefer to stay in the mid-plane of interlayer region and Cs+ and Rb+ are located closer to the basal plane via inner-sphere complexation. Furthermore, the orientations of interlayer UO22+ are nearly perpendicular to basal surface. The effects of temperature, montmorillonite type, interlayer water content, and concentration of nuclide on the exchange processes are further clarified. This study provides fundamental data for a profound understanding of environmental behavior of radionuclides.
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