Journal
JOURNAL OF HAZARDOUS MATERIALS
Volume 314, Issue -, Pages 1-10Publisher
ELSEVIER
DOI: 10.1016/j.jhazmat.2016.04.018
Keywords
Textile-dyeing sludge; Potassium permanganate; Ultrasound technique; Aromatic amines; Degradation
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Funding
- Natural Science Foundation of China [21577027]
- Science and Technology Plan of Guangdong Province [2015A020215032]
- Special Applied Technology Research and Development of Guangdong Province (major project) [2015B020235013]
- Science and Technology Plan of Guangzhou
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This paper reports, for the first time, a combined technique of ultrasound (US) with KMnO4 degradation of aromatic amines in a textile-dyeing sludge. The reaction mechanisms and the degradation kinetics of aromatic amines at various operating parameters (KMnO4 dosage, US power density and pH) were systematically examined by the combined system of US-KMnO4. The results indicated that there was a synergistic effect between US and KMnO4, as US greatly enhanced KMnO4 in the degradation of aromatic amines and exhibited apparent sludge disintegration and separated pollutants from the sludge. In addition to accelerating the Mn(VII) reaction with pollutants in the filtrate, US also caused Mn(VII) to enter the porous sludge and sufficiently facilitated the reaction of the strongly absorbed aromatic amines. The combined treatment of US-KMnO4 was effective in the degradation of aromatic amines in textile-dyeing sludge. On average, 58.7% of monocyclic anilines, 88.3% of other forms of aromatic amines, and 24.0% of TOC were removed under the optimal operating conditions of a KMnO4 dosage of 12 mM, an US power density of 1.80 W/cm(3) and pH 5. The present study proposed US-KMnO4 treatment as a practical method for the disposal of aromatic amines in textile-dyeing sludge. (C) 2016 Elsevier B.V. All rights reserved.
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