Journal
JOURNAL OF HAZARDOUS MATERIALS
Volume 317, Issue -, Pages 617-621Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2016.06.032
Keywords
Coordination polymers; Nanomaterials; Lithium-ion battery; Recycling; Metal extraction
Categories
Funding
- CONACYT
- VEOLIA SARPi
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An innovative approach is proposed for the recycling of metals from a simulant lithium-ion battery (LIBs) waste aqueous solution. Phosphonate organic linkers are introduced as precipitating agents to selectively react with the metals to form coordination polymers from an aqueous solution containing Ni, Mn and Co in a hydrothermal process. The supernatant is analyzed by ICP-AES to quantify the efficiency and the selectivity of the precipitation and the materials are characterized by Scanning Electron Microscopy (SEM), Powder X-Ray Diffraction (PXRD), Thermogravimetric Analyses (TGA) and nitrogen gas sorption (BET). Conditions have been achieved to selectively precipitate Manganese or Manganese/Cobalt from this solution with a high efficiency. This work describes a novel method to obtain potentially valuable coordination polymers from a waste metal solution that can be generalized on any waste solution. (C) 2016 Elsevier B.V. All rights reserved.
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