4.8 Editorial Material

Regioselective Transition-Metal-Free Arene C-H Borylations: From Directing Groups to Borylation Template Reagents

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 61, Issue 40, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202210284

Keywords

Borenium Ions; C-H Borylations; Directed Borylations; Electrophilic Substitutions; Indoles

Funding

  1. University of Namur, the Namur Institute of Structured Matter (NISM) [T.0012.21]
  2. Fond National de la Recherche Scientifique (FRS-FNRS) [T.0012.21]

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This article provides a brief overview of the latest developments in electrophilic C-H borylation reactions of arenes and heteroarenes without transition metals, with a particular focus on the recent advances in highly regioselective C-H borylations of indoles and indolines using borylation template reagents.
The latest developments in the field of electrophilic C-H borylation reactions of arenes and heteroarenes without transition metals are briefly overviewed, with a particular emphasis on the latest advances enabling the highly regioselective C-H borylations of indoles and indolines using borylation template reagents.

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