☆ 4.8 Article

Ultrasmall Copper Nanoclusters in Zirconium Metal-Organic Frameworks for the Photoreduction of CO2

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Related references

Note: Only part of the references are listed.

Review Chemistry, Physical

Micro/Nano-Scaled Metal-Organic Frameworks and Their Derivatives for Energy Applications

Yong-Sheng Wei et al.

Summary: Metal-organic frameworks (MOFs) are crystalline porous materials constructed by organic linkers and metal ions/clusters, with high surface area and functional adjustability, leading to versatile applications. This review focuses on the design and synthesis of 1D, 2D, and 3D MOF nanostructures and their derivatives, discussing promising catalytic applications and energy storage, outlining the challenges and future prospects for this emerging field.

ADVANCED ENERGY MATERIALS (2022)

Add to Collection

Review Chemistry, Physical

Recent Progresses in Metal-Organic Frameworks Based Core-shell Composites

Shan Dai et al.

Summary: Encapsulation of active guest compounds inside metal-organic frameworks (MOFs) can lead to properties beyond those of bare MOFs and/or guest species. Core-shell composites show better accessibility to pores, optimal diffusion of substrate, and prevent aggregation and runoff of active guests, promoting synergistic effects. Advances in synthetic strategies and potential applications, such as environmental catalysis, gas separation, and sensing, are discussed in this review to promote new generations of MOFs based composites for energy-related applications.

ADVANCED ENERGY MATERIALS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Switching Excited State Distribution of Metal-Organic Framework for Dramatically Boosting Photocatalysis

Song Guo et al.

Summary: This study proposes a method to enhance the sensitizing ability of metal-organic frameworks by promoting electron transfer through hierarchical organization and multi-component synergy, leading to improved photocatalytic activity. This work provides a new approach for enhancing solar energy conversion through the molecular-level engineering of sensitizing centers.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Feeding Carbonylation with CO2 via the Synergy of Single-Site/Nanocluster Catalysts in a Photosensitizing MOF

Shanshan Fu et al.

Summary: The integration of cobalt single-site and ultrafine CuPd nanocluster catalysts into a porphyrin-based metal-organic framework for solar-driven carbonylation with CO2 as a C1 source is a promising approach. The composite photocatalysts show efficient CO2 photoreduction and Suzuki/Sonogashira reactions under visible light irradiation, replacing hazardous CO gas and improving product yield and selectivity. These findings provide new insights into sustainable carbonylation reactions using greenhouse gas CO2.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

H-Bond-Mediated Selectivity Control of Formate versus CO during CO2 Photoreduction with Two Cooperative Cu/X Sites

Tian-Ci Zhuo et al.

Summary: By integrating photosensitizers and monometallic catalysts into a metal-organic framework, this study achieved highly selective photoreduction of CO2 to formate and revealed the role of hydrogen bonding in the catalytic process.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Engineering, Environmental

Light-driven enzymatic nanosystem for highly selective production of formic acid from CO2

Senshen Yu et al.

Summary: A light-driven enzymatic nanosystem was developed for the selective production of formic acid from CO2, combining graphitic carbon nitride with natural enzyme catalysts. The system's efficiency is enhanced by encapsulation in a porous metal-organic framework, ensuring high enzyme activity and shortening the distance between enzymes to improve reaction efficiency.

CHEMICAL ENGINEERING JOURNAL (2021)

Add to Collection

Article Chemistry, Physical

Monodispersed MOF-808 Nanocrystals Synthesized via a Scalable Room-Temperature Approach for Efficient Heterogeneous Peptide Bond Hydrolysis

Shan Dai et al.

Summary: Zr(IV)-based metal-organic frameworks (MOFs) such as Zr(IV) trimesate MOF-808 are promising materials for catalytic applications. This work introduces a room-temperature strategy to produce well-defined monodispersed MOF-808 nanocrystals with high space-time yield, excellent crystallinity, and porosity, showing potential for highly efficient peptide or protein hydrolysis.

CHEMISTRY OF MATERIALS (2021)

Add to Collection

Article Chemistry, Physical

Self-adaptive dual-metal-site pairs in metal-organic frameworks for selective CO2 photoreduction to CH4

Jian Li et al.

Summary: The study demonstrates a bioinspired photocatalyst with flexible dual-metal-site pairs that enhance CH4 selectivity and production rate. By stabilizing various C1 intermediates, it achieves a highly selective CO2-to-CH4 process.

NATURE CATALYSIS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Metal-organic frameworks as catalytic selectivity regulators for organic transformations

Jun Guo et al.

Summary: Metal-organic frameworks (MOFs) have shown promising effects in regulating and improving selectivity in organic transformations, by manipulating their catalytic microenvironments. Researchers aim to utilize MOFs for the design and synthesis of high value-added organic chemicals.

CHEMICAL SOCIETY REVIEWS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Two-Dimensional Metal-Organic Framework Nanosheets with Cobalt-Porphyrins for High-Performance CO2 Electroreduction

Xiang-Da Zhang et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Boosting Catalysis of Pd Nanoparticles in MOFs by Pore Wall Engineering: The Roles of Electron Transfer and Adsorption Energy

Dongxiao Chen et al.

ADVANCED MATERIALS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Photoinduction of Cu Single Atoms Decorated on UiO-66-NH2 for Enhanced Photocatalytic Reduction of CO2 to Liquid Fuels

Gang Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Core-Shell Gold Nanorod@Zirconium-Based Metal-Organic Framework Composites as in Situ Size-Selective Raman Probes

Johannes W. M. Osterrieth et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Add to Collection

Article Chemistry, Physical

Continuous 3D Titanium Nitride Nanoshell Structure for Solar-Driven Unbiased Biocatalytic CO2 Reduction

Su Keun Kuk et al.

ADVANCED ENERGY MATERIALS (2019)

Add to Collection

Article Multidisciplinary Sciences

Location determination of metal nanoparticles relative to a metal-organic framework

Yu-Zhen Chen et al.

NATURE COMMUNICATIONS (2019)

Add to Collection

Article Electrochemistry

Decoration of N-functionalized graphene nanoflakes with copper-based nanoparticles for high selectivity CO2 electroreduction towards formate

U. Legrand et al.

ELECTROCHIMICA ACTA (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Electroreduction of CO2 on Single-Site Copper-Nitrogen-Doped Carbon Material: Selective Formation of Ethanol and Reversible Restructuration of the Metal Sites

Dilan Karapinar et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Article Chemistry, Physical

Addressing the characterisation challenge to understand catalysis in MOFs: the case of nanoscale Cu supported in NU-1000

Ana E. Platero-Prats et al.

FARADAY DISCUSSIONS (2017)

Add to Collection

Article Multidisciplinary Sciences

CATALYSIS Active sites for CO2 hydrogenation to methanol on Cu/ZnO catalysts

Shyam Kattel et al.

SCIENCE (2017)

Add to Collection

Article Chemistry, Physical

Addressing the characterisation challenge to understand catalysis in MOFs: the case of nanoscale Cu supported in NU-1000

Ana E. Platero-Prats et al.

FARADAY DISCUSSIONS (2017)

Add to Collection

Article Chemistry, Physical

Graphene oxide/core-shell structured metal-organic framework nano-sandwiches and their derived cobalt/N-doped carbon nanosheets for oxygen reduction reactions

Jing Wei et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

Add to Collection

Article Chemistry, Physical

Surface functionalization of ZIF-8 with ammonium ferric citrate toward high exposure of Fe-N active sites for efficient oxygen and carbon dioxide electroreduction

Yifan Ye et al.

NANO ENERGY (2017)

Add to Collection

Review Chemistry, Multidisciplinary

Metal-organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis

Qihao Yang et al.

CHEMICAL SOCIETY REVIEWS (2017)

Add to Collection

Article Nanoscience & Nanotechnology

A Novel CuxO Nanoparticles@ZIF-8 Composite Derived from Core-Shell Metal-Organic Frameworks for Highly Selective Electrochemical Sensing of Hydrogen Peroxide

Juan Yang et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Boosting Photocatalytic Hydrogen Production of a Metal-Organic Framework Decorated with Platinum Nanoparticles: The Platinum Location Matters

Juan-Ding Xiao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Selective and Efficient Reduction of Carbon Dioxide to Carbon Monoxide on Oxide-Derived Nanostructured Silver Electrocatalysts

Ming Ma et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Copper Nanocrystals Encapsulated in Zr-based Metal-Organic Frameworks for Highly Selective CO2 Hydrogenation to Methanol

Bunyarat Rungtaweevoranit et al.

NANO LETTERS (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Size-Dependent Electrocatalytic Reduction of CO2 over Pd Nanoparticles

Dunfeng Gao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Add to Collection

Article Chemistry, Multidisciplinary

Atomically precise metal nanoclusters: stable sizes and optical properties

Rongchao Jin

NANOSCALE (2015)

Add to Collection

Article Chemistry, Multidisciplinary

Particle Size Effects in the Catalytic Electroreduction of CO2 on Cu Nanoparticles

Rulle Reske et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Add to Collection

Article Chemistry, Physical

Fe-Based MOFs for Photocatalytic CO2 Reduction: Role of Coordination Unsaturated Sites and Dual Excitation Pathways

Dengke Wang et al.

ACS CATALYSIS (2014)

Add to Collection

Article Chemistry, Physical

Tailoring Cu valence and oxygen vacancy in Cu/TiO2 catalysts for enhanced CO2 photoreduction efficiency

Lianjun Liu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2013)

Add to Collection

Article Chemistry, Multidisciplinary

Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO2 to CO

Wenlei Zhu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Add to Collection

Article Chemistry, Multidisciplinary

An Amine-Functionalized Titanium Metal-Organic Framework Photocatalyst with Visible-Light-Induced Activity for CO2 Reduction

Yanghe Fu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Add to Collection

Article Chemistry, Physical

Well-studied Cu-BTC still serves surprises: evidence for facile Cu2+/Cu+ interchange

Janos Szanyi et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2012)

Add to Collection

Article Chemistry, Multidisciplinary

Morphology-Dependent Interactions of ZnO with Cu Nanoparticles at the Materials' Interface in Selective Hydrogenation of CO2 to CH3OH

Fenglin Liao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Add to Collection

Review Materials Science, Multidisciplinary

Synthesis and catalytic properties of metal nanoparticles: Size, shape, support, composition, and oxidation state effects

Beatriz Roldan Cuenya

THIN SOLID FILMS (2010)

Add to Collection

Article Multidisciplinary Sciences

The effect of size-dependent nanoparticle energetics on catalyst sintering

CT Campbell et al.

SCIENCE (2002)

Add to Collection

Article Chemistry, Multidisciplinary

NO and CO adsorption on over-exchanged Cu-MCM-22: A FTIR study

A Frache et al.

LANGMUIR (2002)

Add to Collection

© Peeref 2019-2024. All rights reserved.