Electrochemical Double-Layer Capacitor based on Carbon@ Covalent Organic Framework Aerogels

Article Chemistry, Physical

Band-like Transport of Charge Carriers in Oriented Two-Dimensional Conjugated Covalent Organic Frameworks

Samrat Ghosh et al.

Summary: This study developed crystalline pi-conjugated covalent organic frameworks (COFs) and demonstrated their potential in terms of conductivity and photoresponsivity, providing new active materials for multifunctional organic electronics.

CHEMISTRY OF MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Ultralarge Free-Standing Imine-Based Covalent Organic Framework Membranes Fabricated via Compression

Jesus A. Martin-Illan et al.

Summary: A simple compression method is reported to prepare large-scale, free-standing, homogeneous and porous imine-based COF membranes, which exhibit excellent mechanical and separation performances.

ADVANCED SCIENCE (2022)

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Review Chemistry, Physical

2D Covalent-Organic Framework Electrodes for Supercapacitors and Rechargeable Metal-Ion Batteries

Sharath Kandambeth et al.

Summary: 2D-COFs are promising materials for electrochemical energy storage due to their ordered structure design, tunable pore size, and ability to accommodate mobile ions with different sizes and charges, making them suitable for various types of batteries. Their strong covalently linked framework backbone also provides long cycle life and stability against leaching out in strong electrolytes.

ADVANCED ENERGY MATERIALS (2022)

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Review Chemistry, Multidisciplinary

Current Trends in Metal-Organic and Covalent Organic Framework Membrane Materials

Bahram Hosseini Monjezi et al.

Summary: Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) have been extensively studied for gas separation membranes in recent years. New preparation methods have been developed for MOFs and COFs, as well as for mixed-matrix membranes (MMMs). Unique processes and materials, such as Zeolitic imidazolate frameworks (ZIFs) transforming into glasses and liquids with permanent porosity for manufacturing potent MMMs, have been highlighted. MOF materials influenced by external stimuli offer new directions for performance enhancement using in situ techniques.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Chemistry, Multidisciplinary

Recent Advances of Asymmetric Supercapacitors

Nannan Wu et al.

Summary: This article introduces the structure and material compositions of asymmetric supercapacitors, which are classified into two types: electric double-layer capacitor//pseudocapacitive-type and electric double-layer capacitor//battery-type hybrid, using carbon materials and different metal oxides/hydroxides as anodes and cathodes. Recent advances show that Li-ion-based ASCs have great potential, and the challenges and prospects for the development of ASCs are pointed out.

ADVANCED MATERIALS INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Macroscopic Ultralight Aerogel Monoliths of Imine-based Covalent Organic Frameworks

Jesus A. Martin-Illan et al.

Summary: This study presents a simple three-step method to produce COF aerogels with extremely low densities and high porosity. These COF aerogels exhibit excellent adsorption capacity and removal efficiency, while maintaining the micro- and meso-porosity of the constituent COFs.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Physical

Lignin carbon aerogel/nickel binary network for cubic supercapacitor electrodes with ultra-high areal capacitance

Siqin Guo et al.

Summary: An ultra-thick cubic electrode was successfully fabricated based on LCAN bulk with a binary network structure under ZnCl2 hypersaline conditions. The precise adjustment of ZnCl2/lignin ratio and the combination of LCAN binary network resulted in the cubic electrode with high performance characteristics. Together, these features represent promising 3D thick electrodes for energy-related devices.

CARBON (2021)

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Article Chemistry, Physical

Advanced carbon nanomaterials for state-of-the-art flexible supercapacitors

Ping Xie et al.

Summary: This review comprehensively and systematically expounds the recent progress of state-of-the-art flexible supercapacitors using advanced carbon nanomaterials, covering micro/nano-structure control, macroscopic morphologies design, property optimization, and application. The challenges and prospects of carbon nanomaterials applied in flexible supercapacitors are outlined and emphasized based on the current advances. Additionally, the matching between the characters of carbon nanomaterials, construction of flexible supercapacitors, and fabrication technologies are proposed.

ENERGY STORAGE MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Scalable Fabrication of Crystalline COF Membranes from Amorphous Polymeric Membranes

Chunyang Fan et al.

Summary: The transformation from amorphous polymeric membrane to crystalline COF membrane via monomer exchange allows for improved proton conductivity. The addition of intramolecular hydrogen bonds helps the crystalline COF maintain the morphology of the amorphous membrane.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Chemistry, Multidisciplinary

A Review on the Production Methods and Applications of Graphene-Based Materials

Md Abdullah Al Faruque et al.

Summary: Graphene-based materials, in various forms, have attracted significant research interest due to their exceptional properties and potential applications in diverse fields. Despite the promising results achieved, further research is needed to optimize the performance of graphene-based materials. This review aims to bridge the existing gap in the literature by providing a comprehensive overview of the most commonly used fabrication methods and application areas of graphene-based materials.

NANOMATERIALS (2021)

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Article Chemistry, Physical

Hierarchical porous covalent organic framework/graphene aerogel electrode for high-performance supercapacitors

Ning An et al.

Summary: This study demonstrates the fabrication of a redox-active covalent organic frameworks (COFs)/graphene composite aerogel electrode, which efficiently addresses the low electrical conductivity and sluggish electron transfer issues within the organic framework, showing high specific capacitance and fast kinetics. Moreover, the binder-free redox-active COFs/graphene composite aerogel and pure graphene aerogel are assembled into an asymmetric supercapacitor, achieving excellent performance in energy density and power density.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Review Chemistry, Multidisciplinary

Covalent organic frameworks (COFs) for electrochemical applications

Xiaojia Zhao et al.

Summary: This article introduces the application potential of covalent organic frameworks and discusses the design and synthesis strategies for their use in electrochemical applications. The focus is on the recent development of hybrid COF materials and COFs with hierarchical porosity which can address the challenges in electrochemical applications of COFs. Challenges and future trends in the use of COF materials in electrochemical applications are also outlined.

CHEMICAL SOCIETY REVIEWS (2021)

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Review Chemistry, Physical

Chemical supercapacitors: a review focusing on metallic compounds and conducting polymers

Pappu Naskar et al.

Summary: This review explores the historical progression and recent advancements in the development of chemical supercapacitors, focusing on metallic compounds and conducting polymers. The fabrication of versatile conductive nanocomposites and robust composites for addressing inherent limitations of materials is discussed. Overall, this comprehensive review sheds light on the potential of chemical supercapacitors for future energy storage applications.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Multidisciplinary

Exfoliated Mesoporous 2D Covalent Organic Frameworks for High-Rate Electrochemical Double-Layer Capacitors

Yusran Yusran et al.

ADVANCED MATERIALS (2020)

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Review Chemistry, Physical

Covalent-Organic Frameworks: Advanced Organic Electrode Materials for Rechargeable Batteries

Tao Sun et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Energy & Fuels

Graphene Based Aerogels: Fundamentals and Applications as Supercapacitors

Yasir Beeran Pottathara et al.

JOURNAL OF ENERGY STORAGE (2020)

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Review Chemistry, Multidisciplinary

Two-Dimensional Carbon-Rich Conjugated Frameworks for Electrochemical Energy Applications

Minghao Yu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Multidisciplinary Sciences

Ultralight covalent organic framework/graphene aerogels with hierarchical porosity

Changxia Li et al.

NATURE COMMUNICATIONS (2020)

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Review Chemistry, Multidisciplinary

Emerging 2D MXenes for supercapacitors: status, challenges and prospects

Minmin Hu et al.

CHEMICAL SOCIETY REVIEWS (2020)

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Article Chemistry, Physical

Choosing the right carbon additive is of vital importance for high-performance Sb-based Na-ion batteries

Kristina Pfeifer et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Multidisciplinary

Inducing Disorder in Order: Hierarchically Porous Covalent Organic Framework Nanostructures for Rapid Removal of Persistent Organic Pollutants

Suvendu Karak et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Nanoscience & Nanotechnology

Ultrastable Triazine-Based Covalent Organic Framework with an Interlayer Hydrogen Bonding for Supercapacitor Applications

Li Li et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Multidisciplinary

An Olefin-Linked Covalent Organic Framework as a Flexible Thin-Film Electrode for a High-Performance Micro-Supercapacitor

Junsong Xu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Nanoscience & Nanotechnology

Weak Intermolecular Interactions in Covalent Organic Framework-Carbon Nanofiber Based Crystalline yet Flexible Devices

Abdul Khayum Mohammed et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Review Chemistry, Multidisciplinary

Electrolyte selection for supercapacitive devices: a critical review

Bhupender Pal et al.

NANOSCALE ADVANCES (2019)

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Article Chemistry, Physical

Physical Interpretations of Nyquist Plots for EDLC Electrodes and Devices

Bing-Ang Mei et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2018)

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Article Chemistry, Multidisciplinary

Ultrastable Imine-Based Covalent Organic Frameworks for Sulfuric Acid Recovery: An Effect of Interlayer Hydrogen Bonding

Arjun Halder et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Article Electrochemistry

Impedance modeling of silica nanoparticle metal insulator metal capacitors

Bremnen Veliz et al.

ELECTROCHIMICA ACTA (2018)

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Review Green & Sustainable Science & Technology

A review of supercapacitor modeling, estimation, and applications: A control/management perspective

Lei Zhang et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2018)

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Emergent Pseudocapacitance of 2D Nanomaterials

Xu Yu et al.

ADVANCED ENERGY MATERIALS (2018)

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Review Chemistry, Multidisciplinary

Hollow Structural Transition Metal Oxide for AdvancedSupercapacitors

Jilei Wei et al.

ADVANCED MATERIALS INTERFACES (2018)

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Article Nanoscience & Nanotechnology

Convergent Covalent Organic Framework Thin Sheets as Flexible Supercapacitor Electrodes

Abdul M. Khayum et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

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Microporosity-Controlled Synthesis of Heteroatom Codoped Carbon Nanocages by Wrap-Bake-Sublime Approach for Flexible All-Solid-State-Supercapacitors

Vinayak S. Kale et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

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Conductive MOF electrodes for stable supercapacitors with high areal capacitance

Dennis Sheberla et al.

NATURE MATERIALS (2017)

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Review Multidisciplinary Sciences

The atom, the molecule, and the covalent organic framework

Christian S. Diercks et al.

SCIENCE (2017)

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Metal-functionalized covalent organic frameworks as precursors of supercapacitive porous N-doped graphene

Jorge Romero et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

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High-Level Supercapacitive Performance of Chemically Reduced Graphene Oxide

Plawan Kumar Jha et al.

CHEM (2017)

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Syntheses and Energy Storage Applications of MxSy (M = Cu, Ag, Au) and Their Composites: Rechargeable Batteries and Supercapacitors

Yao Lu et al.

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Isoreticular covalent organic frameworks for hydrocarbon uptake and separation: the important role of monomer planarity

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Measuring and Reporting Electrical Conductivity in Metal Organic Frameworks: Cd2(TTFTB) as a Case Study

Lei Sun et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

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2D Materials Beyond Graphene for High-Performance Energy Storage Applications

Xiaoyan Zhang et al.

ADVANCED ENERGY MATERIALS (2016)

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Graphene-based materials for flexible supercapacitors

Yuanlong Shao et al.

CHEMICAL SOCIETY REVIEWS (2015)

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Creation of Superheterojunction Polymers via Direct Polycondensation: Segregated and Bicontinuous Donor-Acceptor π-Columnar Arrays in Covalent Organic Frameworks for Long-Lived Charge Separation

Shangbin Jin et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

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Phosphoric Acid Loaded Azo (-N=N-) Based Covalent Organic Framework for Proton Conduction

Suman Chandra et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

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Graphene and Graphene-Based Materials for Energy Storage Applications

Jixin Zhu et al.

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Superior supercapacitive performance in electrospun copper oxide nanowire electrodes

Baiju Vidhyadharan et al.

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β-Ketoenamine-Linked Covalent Organic Frameworks Capable of Pseudocapacitive Energy Storage

Catherine R. DeBlase et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

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Graphene for supercapacitor applications

Yu Bin Tan et al.

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Insights into the influence of pore size distribution and surface functionalities in the behaviour of carbon supercapacitors

Susana Vaquero et al.

ELECTROCHIMICA ACTA (2012)

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Highly Conductive and Porous Activated Reduced Graphene Oxide Films for High-Power Supercapacitors

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NANO LETTERS (2012)

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Opportunities and challenges for a sustainable energy future

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CHEMICAL REVIEWS (2011)

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Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon

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Confinement of Symmetric Tetraalkylammonium Ions in Nanoporous Carbon Electrodes of Electric Double-Layer Capacitors

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JOURNAL OF PHYSICAL CHEMISTRY C (2009)

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Electrochemical characteristics and impedance spectroscopy studies of carbon-carbon supercapacitors

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Electrochemical Double-Layer Capacitor based on Carbon@ Covalent Organic Framework Aerogels

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