4.8 Article

3D Printed Platform for Impedimetric Sensing of Liquids and Microfluidic Channels

Journal

ANALYTICAL CHEMISTRY
Volume 94, Issue 41, Pages 14426-14433

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.analchem.2c03191

Keywords

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Funding

  1. Czech Academy of Sciences [RVO: 61388955, L200402251]
  2. Czech Science Foundation [20-01589S]
  3. Specific University Research [SVV260560]
  4. Grant Agency of the Charles University [373521]
  5. National Science Centre of Poland [UMO-2018/31/D/ST4/03259]
  6. Slovak Research and Development Agency [APVV-18-0075]
  7. VEGA grant agency [2/0019/19, 1/0227/20]

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Fused deposition modeling 3D printing using electrically conductive filaments is an attractive tool for manufacturing sensing devices. This study explores the capabilities of 3D printed electrodes to measure electric properties of materials. The authors demonstrate the functionality of a bimaterial FDM-3DP platform for sensing conductivity and permittivity of liquids by impedance measurements. Additionally, they propose an original idea of using impedance measurements to investigate dimensions of 3D printed channels as base structures of microfluidic devices, complemented by optical microscopic analysis.
Fused deposition modeling 3D printing (FDM-3DP) employing electrically conductive filaments has recently been recognized as an exceptionally attractive tool for the manufacture of sensing devices. However, capabilities of 3DP electrodes to measure electric properties of materials have not yet been explored. To bridge this gap, we employ bimaterial FDM-3DP combining electrically conductive and insulating filaments to build an integrated platform for sensing conductivity and permittivity of liquids by impedance measurements. The functionality of the device is demonstrated by measuring conductivity of aqueous potassium chloride solution and bottled water samples and permittivity of water, ethanol, and their mixtures. We further implement an original idea of applying impedance measurements to investigate dimensions of 3DP channels as base structures of microfluidic devices, complemented by their optical microscopic analysis. We demonstrate that FDM-3DP allows the manufacture of microchannels of width down to 80 mu m.

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