Controlling Surface Contact, Oxygen Transport, and Pitting of Surface Oxide via Single-Channel Scanning Electrochemical Cell Microscopy

In single-channel scanning electrochemical cell microscopy, the applied potential during the approach of a micropipette to the substrate generates a transient current upon droplet contact with the substrate. Once the transient current exceeds a set threshold, the micropipette is automatically halted. Currently, the effect of the approach potential on the subsequent electrochemical measurements, such as the open-circuit potential and potentiodynamic polarization, is considered to be inconsequential. Herein, we demonstrate that the applied approach potential does impact the extent of probe-to-substrate interaction and subsequent microscale electro-chemical measurements on aluminum alloy AA7075-T73.

Automated summary

The applied approach potential in single-channel scanning electrochemical cell microscopy affects the interaction between the probe and substrate, as well as subsequent microscale electrochemical measurements.