4.8 Article

Versatile Hole Selective Molecules Containing a Series of Heteroatoms as Self-Assembled Monolayers for Efficient p-i-n Perovskite and Organic Solar Cells

Journal

ADVANCED FUNCTIONAL MATERIALS
Volume 32, Issue 49, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202208793

Keywords

highly efficient; organic solar cells; OSCs; perovskite solar cells; PSCs; SAMs; Self-assembled monolayers; stability

Funding

  1. Research and Development Program of the Korea Institute of Energy Research (KIER) [C2-2402]
  2. National Research Foundation of Korea (NRF) - Korean Government [NRF-2019R1F1A1062540, NRF-2020M1A2A2080746, NRF-2018R1A5A1025594]

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Inverted perovskite solar cells offer advantages such as easy processing and high stability, but face challenges in achieving high power conversion efficiency. This study introduces excellent hole-selective materials for inverted PSCs and demonstrates the potential of engineered self-assembled monolayers (SAMs) in achieving high-performance solar cells. The Se-containing SAM shows the strongest interaction with the perovskite absorber and achieves a PCE of 22.73%.
Inverted type perovskite solar cells (PSCs) have recently emerged as a major focus in academic and industrial photovoltaic research. Their multiple advantages over conventional PSCs include easy processing, hysteresis-free behavior, high stability, and compatibility for tandem applications. However, the maximum power conversion efficiency (PCE) of inverted PSCs still lags behind those of conventional PSCs because suitable charge-selective materials for inverted PSCs are limited. In this work, excellent hole-selective materials for inverted PSCs are introduced. A series of tricyclic aromatic rings containing O, S, or Se, respectively, as a core heteroatom, along with a phosphonic acid anchor, form a self-assembled monolayer (SAM) that directly contacts the perovskite absorber. The influence of heteroatoms in the aromatic structure on the molecular energetics and operating characteristics of the corresponding inverted PSCs is investigated using complementary experimental techniques as well as density functional theory (DFT) calculations. It is found that all of the SAMs formed an energetically well-aligned interface with the perovskite absorber. The interaction energy between the Se-containing SAM and perovskite absorber is the strongest among the series and it reduces the interfacial defect density, in turn leading to an extended charge carrier lifetime. As a result, PSCs incorporating the Se-containing SAM achieves a PCE of 22.73% and retains approximate to 96% of their initial efficiency after a maximum power point tracking test of 500 h without encapsulation under ambient conditions. All of the SAMs are then employed in organic solar cells (OSCs). Again, the Se-containing SAM-based OSCs demonstrates the highest PCE of 17.9% among the three molecular SAM-based OSCs. This work demonstrates the great potential for precisely engineered SAMs for use in high-performance solar cells.

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