Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 14, Issue 42, Pages 47716-47724Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.2c12962
Keywords
aqueous dual-ion battery cathode; zinc batteries; coordination supramolecular networks; anchoring I-3(-); charge-transfer interaction
Funding
- National Natural Science Foundation of China
- Natural Science Foundation of Guangdong Province
- [91022012]
- [51472275]
- [2021A1515010371]
- [2014A030313207]
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This study investigates the charge-transfer interaction between I-3(-) and pyrimidine nitrogen based on molecular orbital theory, with experimental and computational results supporting the proposed mechanism. It provides a new direction for research on high-performance cathode materials for iodine batteries.
Iodine is considered to have broad application prospects in the field of electrochemical energy storage. However, the high solubility of I-3(-) severely hampers its practical application, and the lack of research on the anchoring mechanism of I-3(-) has seriously hindered the development of advanced cathode materials for iodine batteries. Herein, based on the molecular orbital theory, we studied the charge-transfer interaction between the acceptor of I-3(-) with sigma* empty antibonding orbital and the donor of pyrimidine nitrogen with lone-pair electrons, which is proved by the results of UV-vis absorption spectroscopy, Raman spectroscopy, and density functional theory (DFT) calculations. The prepared dual-ion battery (DIB) exhibits a high voltage platform of 1.2 V, a remarkable discharge-specific capacity of up to 207 mAh g(-1), and an energy density of 233 Wh kg(-1) at a current density of 5 A g(-1), as well as outstanding cycle stability (operating stably for 5000 cycles) with a high Coulombic efficiency of 97%, demonstrating excellent electrochemical performance and a promising prospect in stationary energy storage.
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