Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 14, Issue 42, Pages 47578-47586Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.2c11680
Keywords
lithium-ion battery separator; mechanical property; nanoindentation; elastic modulus; hardness
Funding
- National Natural Science Foundation of China
- Jilin Science and Technology Development Plan Project
- [51875241]
- [YDZJ202101-ZYTS129]
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The evolution of mechanical properties of separators affected by temperature shifts was experimentally verified in this study. The temperature-dependent weakening of elastic modulus and hardness of separators was observed. The variation trends of elastic modulus, hardness, and hysteresis response of the separators were investigated through nanoindentation tests. X-ray diffraction and energy-dispersive X-ray spectroscopy were used to analyze the temperature-induced residual stress and elemental distribution. The obtained evolution law of temperature shift-induced mechanical properties of separators could facilitate the optimal design of separators and enhance the safety performance of lithium-ion batteries.
The evolution of mechanical properties of separators affected by temperature shifts is imperative for the performance of the lithium-ion battery. The flexible film characteristics hinder the evaluation of the micromechanical properties of separators. In the present study, considering the susceptibility of separators to temperature fluctuations, the temperature distribution of the battery during the discharging process at subzero temperature is obtained. Three sets of separator samples subjected to various temperature shifts are prepared. Through multicycle depth-sensitive nanoindentation, the temperature-dependent weakening of elastic modulus and hardness of separators is experimentally verified. Moreover, the variation trends of elastic modulus, hardness, and hysteresis response of the separator specimens in terms of temperature are investigated via extracting from the multicycle loading-unloading nanoindentation responses. The temperature-dependent variations in the elastic modulus of the separator were investigated by following heating, cooling, and thermostatic processes. Meanwhile, the indentation tests also verify that the effect of temperature shifts on the hardness exhibits an attenuation trend when heating or cooling is followed by a thermostatic process. The variation analysis of nanoindentation hardness as a function of temperature shifts shows typical size effects dependent on the nanoindentation depth. The temperature-induced residual stress and elemental distribution are also analyzed through characterization using X-ray diffraction and energy-dispersive X-ray spectroscopy, respectively. The obtained evolution law of temperature shift-induced mechanical properties of a separator could facilitate the optimal design of the separators and provide the supporting data to enhance the safety performance of lithium-ion batteries.
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