4.8 Article

In Situ Activation of Superhydrophobic Surfaces with Triple Icephobicity at Low Temperatures

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 14, Issue 43, Pages -

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.2c15075

Keywords

superhydrophobic; triple icephobicity; water-repellent; heat loss rate; three-phase contact line

Funding

  1. National Natural Science Foundation of China [11972124]
  2. Special Fund for Basic Scientific Research in Central Universities of China-Doctoral Research and Innovation Fund Project [3072022GIP0201]
  3. China Scholarship Council [202106680048]
  4. Natural Science Youth Funds of Jiangsu Province [BK20220554]

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This study prepares superhydrophobic surfaces with heating capability and excellent water-repellent, anti-icing, and icephobic performances at low temperatures. The triple icephobicity can be activated even at low temperatures by applying voltage. The heating property of the superhydrophobic surface can release the mechanical interlocking force between the surface and ice.
Superhydrophobic surfaces have been widely studied due to their potential applications in aerospace fields. However, super hydrophobic surfaces with excellent water-repellent, anti-icing, and icephobic performances at low temperatures have rarely been reported. Herein, superhydrophobic surfaces with heating capability were prepared by etching square micropillar arrays on the surface of multiwalled carbon nanotube (MWCNT)/poly(dimethylsiloxane) (PDMS) films. The fabricated superhydrophobic surface has triple icephobicity, which can be activated even at low temperatures. The triple icephobicity is triggered by an applied voltage to achieve excellent water-repellent and icephobic capabilities, even at -40 & DEG;C. Additionally, theoretical calculations reveal that a droplet on a superhydrophobic surface loses heat at a rate of 8.91 x 10-5 J/s, which is 2 orders of magnitude slower than a flat surface (2.15 x 10-3 J/s). Also, at -40 & DEG;C, the mechanical interlocking force formed between the superhydrophobic surface and ice can be released by the heating property of the superhydrophobic surface. This low-energy, multifunctional superhydrophobic surface opens up new possibilities for bionic smart multifunctional materials in icephobic applications.

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