4.8 Article

Solution Processed Photodetectors with PVK-WS2 Nanotube/Nanofullerene Organic-Inorganic Hybrid Films

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume -, Issue -, Pages -

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.2c10745

Keywords

photodetectors; organic-inorganic hybrid films; tungsten disulfide nanotubes; tungsten disulfide nanofullerenes; optoelectronic devices; organic-inorganic hybrid materials

Funding

  1. National Key R&D Program of China [2021 Y F B 2 8 0 0 7 0 0, 2021 Y F B 2 8 0 0 7 0 3, 2021YFB2800701]
  2. National Natural Science Foundation of China (NSFC) [61875241, 61975219]
  3. Chinese Academy of Sciences

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Organic-inorganic hybrid photodetectors, with exceptional properties, have attracted increased interest for various applications. In this study, photodetectors were fabricated using hybrid thin films containing one-dimensional and zero-dimensional WS2 nanomaterials mixed with PVK, showing high sensitivity and stable voltage responses to visible light.
Organic-inorganic hybrid photodetectors have attracted increased interest due to their exceptional properties, such as flexibility, transparency, and low cost for many promising applications. Low-dimensional tungsten disulfide (WS2) nano-structures have outstanding electrical and optical properties, making them ideal candidates for ultrasensitive photodetector devices. In this paper, photodetectors were fabricated with hybrid thin films containing two different WS2 nanomaterials, one-dimensional (1D) WS2 nanotubes (WS2-NTs) and a zero-dimensional (0D) WS2 nanofullerene (WS2-FLs) hybrid with poly(N-vinyl carbazole) (PVK). The electrical responses of the devices under visible-light illuminations were studied. The photodetector devices with 0D WS2-FLs/PVK hybrid thin films have relatively higher sensitivity and stable voltage responses to visible light. Besides, the hybrid film shows a strong surface-enhanced Raman effect (SERS). These materials and new strategies enable the creation of a new class of processed photodetectors for practical applications.

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