Structural and Electronic Modulation of Iron-Based Bimetallic Metal-Organic Framework Bifunctional Electrocatalysts for Efficient Overall Water Splitting in Alkaline and Seawater Environment

Metal-organic frameworks (MOFs) are considered potential electrocatalysts for efficient water splitting. However, the structure-activity relationship of most MOFs is not systematically analyzed for electrocatalysis for anodes and cathodes. In this paper, we provide a strategy to modulate the electronic microstructure of iron-based bimetallic MOFs (MFe-BDC (M: Mg, Zn, Cd)) grown on the nickel foam (NF) as bifunctional electrocatalysts for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). The optimal bimetallic CdFe-BDC via modulating appropriate metal cations of IIA and IIB possesses excellent OER and HER performance with the lowest overpotentials of 290 mV at 100 mA cm(-2) and 148 mV at 10 mA cm(-2), respectively. The overall water splitting performance of the as-prepared CdFe-BDC requires 1.68 V to achieve a current density of 10 mA cm(-2) in the real seawater media, and it exhibits the competitive H-2 and O-2 production rates of 6.4 and 3.1 mu L s(-1), respectively, in ambient alkaline conditions, suggesting its potential practical applications. Density functional theory (DFT) calculations demonstrate the relationship between microstructure and electrocatalytic performance of bimetallic MFe-BDC. This work emphasizes the significance of tailoring the electronic microstructure of bimetallic MOFs for efficient overall water splitting in alkaline and seawater environment.

Automated summary

In this paper, a strategy to modulate the electronic microstructure of iron-based bimetallic MOFs for efficient water splitting is proposed. The optimal bimetallic MOFs demonstrated excellent electrocatalytic performance for oxygen and hydrogen evolution reactions. These findings highlight the importance of tailoring the electronic microstructure of bimetallic MOFs for efficient overall water splitting in alkaline and seawater environments.