4.8 Article

Superhydrophobic Polyurethane Membrane with a Biomimetically Hierarchical Structure for Self-Cleaning

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume -, Issue -, Pages -

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.2c13208

Keywords

biomimetic hierarchies; superhydrophobicity; self-cleaning; microspheres; electrospinning; electrospraying

Funding

  1. Major Project of Natural Science Research of Jiangsu Higher Education Institutions
  2. Science and Technology Guiding Project of China National Textile and Apparel Council
  3. Foundation Project of Jiangsu Advanced Textile Engineering Technology Center
  4. Youth Innovation Promotion Association, CAS
  5. [22KJA540002]
  6. [2020064]
  7. [XJFZ/2021/3]

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In this study, a stable and durable super hydrophobic film with good self-cleaning performance and chemical resistance was successfully prepared. It also exhibited strong mechanical stability and breathability.
In this study, a stable and durable hexadecyltrimethoxysilane (HDTMS)/thermoplastic polyurethane (TPU) super hydrophobic film is successfully prepared by a simple and low-cost two-step method, namely, carrying out biomimetically hierarchical structures and low surface energy material modification concurrently. Meanwhile, effective parameters affecting the water contact angle (WCA) are studied and optimized. More importantly, under optimum parameters, the maximum WCA is 165 degrees, the minimum slide angle (SA) is 3 degrees, and the adhesion force is 13 mu N, showing good self-cleaning performance. Besides, considerable mechanical stability to withstand 4000 tension or 5000 compression cycles, breathability, and moisture penetrability, as well as chemical resistance with sustained superhydrophobic properties in various harsh environments, are presented.

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