Journal
CURRENT OPINION IN ELECTROCHEMISTRY
Volume 34, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.coelec.2022.100985
Keywords
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Funding
- Chinese Ministry of Science and Technology [2018YFC1602802]
- National Natural Science Foundation of China [22032004, 21773197, 21533006, 21703183]
- Funds of State Key Laboratory of Physical Chemistry of Solid surface and Fujian Science and Technology Office
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In this review, we discuss the latest progress on plasmon-mediated chemical reactions of organic molecules such as para-aminothiophenol, substituted para-aminothiophenol and para-nitrothiophenol at nanostructures modified noble metal electrodes using surface enhanced Raman spectroscopy, electrochemical methods, and theoretical calculations.
Plasmonic noble metal nanostructures have been targeted due to their strong surface plasmon resonance at photo electrochemical interfaces. Recently, it has been concluded that, the plasmonic noble metal nanostructures on photoexcitation permit the transfer of effective hot carriers (hot electron/ hole pair) to nearby adsorbed molecules where, the transformed hot carriers can efficiently decrease the activation barrier of a reaction. In this review, our recent achievements in the plasmon-mediated chemical reactions of organic molecules such as para-aminothiophenol, substituted para-aminothiophenol and para-nitrothiophenol at nanostructures modified noble metal electrodes using surface enhanced Raman spectroscopy, electrochemical methods, and theoretical calculations will be discussed.
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