4.7 Review

Salt hydrate phase change materials: Current state of art and the road ahead

Journal

JOURNAL OF ENERGY STORAGE
Volume 51, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.est.2022.104360

Keywords

Thermal energy storage; Phase change material; Salt hydrate; Supercooling; Thermal conductivity; Shape stabilized phase change material

Categories

Funding

  1. MHRD (Ministry of Human Resources Development, India) Plan grant
  2. IIT Roorkee [OH-35-71-142]
  3. [2019-20]

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This article discusses the potential of phase change materials as thermal energy storage materials. It analyzes the current status, commercial requirements, and performance improvements of salt hydrate phase change materials. Compared to organic phase change materials, salt hydrate phase change materials have better performance and a more sustainable supply. However, there are still limitations that need to be addressed through further research. Shape stabilized composites are considered as an effective strategy to improve the performance properties of salt hydrate phase change materials.
Due to high energy storage densities and reduced requirement of maintenance or moving parts, phase change materials are believed to have great potential as thermal energy storage materials. Salt hydrate phase change materials have been relevant since the earliest commercial deployment of latent heat thermal energy storage solutions, however a deeper look into the present standing, commercial requirements and performance improvements of this class of materials indicates that their capabilities have remained underdeveloped, and their advantages, underleveraged. These phase change materials have better thermal performance, better flame retardance, lower manufacturing costs, and a more sustainable supply than their organic counterparts, although a few limitations still exist, often hampering a more widespread adoption. As such, much research in recent years has been focused on eliminating these shortcomings. Presently, all these challenges are critically reviewed, and relevant mitigation/enhancement strategies are also discussed. In the purview of this discussion, shape stabilized composites arise as a singular strategy to alleviate the performance properties of salt hydrate phase change materials across multiple dimensions. A detailed review on the advantages offered by shape stabilized phase change materials is presented along with relevant development studies reported in the literature. Altogether, the reported information provides a perspective towards commercial realization of salt hydrate phase change materials in a wide range of applications, spanning from cold chain logistics to textile incorporation and building materials to solar heating solutions.

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