Journal
CHEMISTRYSELECT
Volume 7, Issue 29, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.202201201
Keywords
1,2,4-Oxadiazoles; Amidoximes; Isatoic anhydride; Luminescent scaffold; Solvatochromism
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Funding
- Russian Science Foundation [20-73-00203]
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This study synthesized and studied a series of organic luminophores with different structures under specific conditions. The results showed that 2-(ortho-aminophenyl) 1,2,4-oxadiazoles are the best luminophores.
Condensation of amidoximes 1 with isatoic anhydrides 2 or esters 3 in NaOH/DMSO medium afforded to substituted 1,2,4-oxadiazolyl anilines. The compounds synthesized can exhibit luminescence, the presence and efficiency of which depends on the position of the amino group in these aminophenyl 1,2,4-oxadiazol derivatives. The best luminophores are 2-(ortho-aminophenyl) 1,2,4-oxadiazoles. More than 20 examples of the new organic luminophores were synthesized and studied. The effect of the luminophore structure on the emission band and on the quantum yield indicates that a luminescent scaffold has been obtained.
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