4.6 Review

Advances in Perovskites for Photovoltaic Applications in Space

Journal

ACS ENERGY LETTERS
Volume 7, Issue 8, Pages 2490-2514

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsenergylett.2c01099

Keywords

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Funding

  1. PRIN 2017 MULTI-e [20179337R7]
  2. European Union's Horizon 2020 Research Innovation Program [GrapheneCore3 881603]
  3. Dottorati FSE XXXVI ciclo Unime [CIP 2014.IT.05. SFOP.014/3/10.5/9.2.10/0002 CUP G47C20000190002]

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Perovskite solar cells have the potential to be used in space technologies due to their thin, lightweight, low-cost, and flexible nature. However, the high-energy radiation in the extraterrestrial environment can cause premature failure of these devices. This review discusses the status and perspectives of perovskite photovoltaics in space applications, including the radiation hardness of perovskites and the effects of the space environment on device architecture and components.
Perovskites have emerged as promising light harvesters in photovoltaics. The resulting solar cells (i) are thin and lightweight, (ii) can be produced through solution processes, (iii) mainly use low-cost raw materials, and (iv) can be flexible. These features make perovskite solar cells intriguing as space technologies; however, the extra-terrestrial environment can easily cause the premature failure of devices. In particular, the presence of highenergy radiation is the most dangerous factor that can damage space technologies. This Review discusses the status and perspectives of perovskite photovoltaics in space applications. The main factors used to describe the space environment are introduced, and the results concerning the radiation hardness of perovskites toward protons, electrons, neutrons, and gamma-rays are presented. Emphasis is given to the physicochemical processes underlying radiation damage in such materials. Finally, the potential use of perovskite solar cells in extra-terrestrial conditions is discussed by considering the effects of the space environment on the choice of the architecture and components of the devices.

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