4.6 Article

Flame Retardancy Performance of Continuous Glass-Fiber-Reinforced Polypropylene Halogen-Free Flame-Retardant Prepreg

Journal

COATINGS
Volume 12, Issue 7, Pages -

Publisher

MDPI
DOI: 10.3390/coatings12070976

Keywords

polypropylene; continuous glass fiber; intumescent flame retardant; unidirectional prepreg; thermoplastic composites

Funding

  1. Fundamental Research Funding [514010104-302]
  2. National Natural Science Foundation of China [11872086]

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This study investigated the effect of adding flame retardant on the impregnation quality of prepreg tape. By adding high-flow polypropylene to improve the melt viscosity of flame-retardant-modified polypropylene, continuous glass-fiber-reinforced polypropylene flame-retardant prepreg tape was successfully prepared. The tests showed that adding 25 wt% intumescent flame retardant (IFR) achieved the best flame retardancy grade.
Thermoplastic resin matrix has a high melt viscosity, which is difficult to impregnate with fibers. The addition of flame retardant will further increase the viscosity of the melt and increase the difficulty of impregnation. It is possible to reduce the effect of flame retardant on melt viscosity by adding high-flow polypropylene. In this study, the effect of adding flame retardant on the impregnation quality of prepreg tape was investigated. By adding high-flow polypropylene to improve the melt viscosity of flame-retardant-modified polypropylene, continuous glass-fiber-reinforced polypropylene flame-retardant prepreg tape was successfully prepared. Intumescent flame retardant (IFR) was added at 20 wt%, 25 wt%, 30 wt% of the polypropylene matrixes, which were prepared by melt impregnation. The composites were analyzed with thermogravimetric analysis, limiting oxygen index testing, UL-94 flame retardancy testing, cone calorimeter testing (CCT) and scanning electron microscopy. Tests involving the flame retardant showed that when the added amount of flame retardant reached 25%, the UL-94 flame retardancy grade reached V0. Compared with the CCT sample heating data, taking economic considerations into account, 25 wt% IFR addition was the most suitable.

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