Investigation of adsorption of Rhodamine B onto a natural adsorbent Argemone mexicana

The present study aims at exploring the potential of the seeds of a tropical weed, Argemone mexicana (AM), for the removal of a toxic xanthene textile dye, Rhodamine B (RHB), from waste water. Impact of pH, adsorbent dosage, particle size, contact time and dye concentration have been assessed during adsorption. The weed has been well characterized by several latest techniques thereby providing an indepth information of the mechanism during adsorption. About 80% removal has been attained with 0.06 g of adsorbent over the studied system. Thermodynamic and kinetic studies, followed by second order kinetic model, directed towards the endothermic nature of adsorption. The results obtained from batch experiments were modelled using Langmuir and Freundlich isotherm and were analysed on the basis of R-2 and six error functions for selection of appropriate model. Langmuir isotherm was found to be best fitted to the experimental data with high values of R-2 and lower values of error functions. Adsorption study revealed the affinity of AM seeds for the dye ions present in waste water, introducing a novel adsorbent in field of waste water treatment. (C) 2016 Elsevier Ltd. All rights reserved.