4.6 Article

Boosted spatial charge carrier separation of binary ZnFe2O4/S-g-C3N4 heterojunction for visible-light-driven photocatalytic activity and antimicrobial performance

Journal

FRONTIERS IN CHEMISTRY
Volume 10, Issue -, Pages -

Publisher

FRONTIERS MEDIA SA
DOI: 10.3389/fchem.2022.975355

Keywords

binary heterojunction; synergic effects; photocatalysis; spatial charge separation; antimicrobial activity

Funding

  1. Deanship of Scientific Research at Umm Al-Qura University [22UQU4320141DSR17]
  2. Research Center at Al-Maarefa University [TUMA-2021-22]
  3. Princess Nourah bint Abdulrahman University Researchers Supporting Project, Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia [PNURSP 2022R53]

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A simple technique for producing zinc ferrite nanoparticles (ZnFe2O4 NPs) with varying quantities of sulphur doped graphitic carbon nitride nanocomposites (ZnFe2O4/S-g-C3N4 NCs) has been described in this study. The photo-catalytic activity of the produced nanoparticles and nanocomposites was examined using various techniques, and it was found that ZnFe2O4/S-g-C3N4 NCs exhibited superior photocatalytic behavior due to synergic effects. In addition, these nanocomposites showed promise as antibacterial agents.
A potential method for removing toxins from contaminated wastewater, especially organic pollutants, is photo-catalysis. Here, a simple technique for producing zinc ferrite nanoparticles (ZnFe2O4 NPS) with varying quantities of sulphur doped graphitic carbon nitride nanocomposites (ZnFe2O4/S-g-C3N4 NCs) has been described. Then, using X-ray diffraction (XRD), TEM, EDX, XPS, photocurrent response, EIS, and Fourier Transform Infrared spectroscopy (FTIR), the photo-catalytic activity of the produced nanoparticles (NPs) and nanocomposites (NCs) was examined and evaluated. The photo-catalytic activity of ZnFe2O4/S-g-C3N4 NCs was compared to a model pollutant dye, methylene blue, while degradation was evaluated spectrophotometrically (MB). Solar light has been used through irradiation as a source of lighting. The photocatalytic behaviour of the ZnFe2O4/S-g-C3N4 NCs photocatalyst was superior to that of genuine ZnFe2O4 and S-g-C3N4, which was attributed to synergic effects at the ZnFe2O4/S-g-C3N4 interconnection. Antimicrobial activity of ZnFe2O4/S-g-C3N4 against Gram-positive and Gram-negative bacteria under visible light was performed. In addition, these ZnFe2O4/S-g-C3N4 NCs show a lot of promise as an antibacterial agent.

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