☆ 4.7 Article

Guest-responsive thermal expansion in the Zr-porphyrin metal-organic framework PCN-222

APL MATERIALS (2022)

Related references

Note: Only part of the references are listed.

Review Chemistry, Inorganic & Nuclear

Negative thermal expansion in framework structure materials

Naike Shi et al.

Summary: Negative thermal expansion (NTE) is a counterintuitive phenomenon where unit cell volume of materials contracts upon heating. Framework structure materials, with flexible bridging units and large voids, facilitate transverse atomic vibrations leading to NTE. The magnitude of NTE is influenced by framework size and metal atom size, and can be controlled through chemical substitution, local structure distortion, and guest molecular or ion intercalation.

COORDINATION CHEMISTRY REVIEWS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Hybrid Perovskites, Metal-Organic Frameworks, and Beyond: Unconventional Degrees of Freedom in Molecular Frameworks

Hanna L. B. Bostroem et al.

Summary: The article discusses the structural degrees of freedom in solid materials and the control of these distortions to produce useful collective functional responses, such as the asymmetric displacements in ferroelectrics and collective rotations in oxide ceramics. It highlights the strategy of generating new materials by combining different distortion types through the interplay between them.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

Add to Collection

Article Chemistry, Multidisciplinary

The Molecular Path Approaching the Active Site in Catalytic Metal-Organic Frameworks

Ana E. Platero-Prats et al.

Summary: The study used in situ synchrotron X-ray scattering analysis to evaluate the binding sites for reagent and product molecules near catalytic Ni-oxo clusters in NU-1000 with different surface functionalization, showing a correlation with ethylene hydrogenation activity. The most active catalyst had ethylene reagent molecules binding close to the catalytic clusters only at temperatures near the experimentally observed onset of catalysis, while ethane product molecules favored a different binding location.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Inorganic & Nuclear

A Porous Coordination Polymer Showing Guest-Amplified Positive and Negative Thermal Expansion

Zi-Ming Ye et al.

Summary: The solvothermal reaction yielded a porous coordination polymer with a fence-like coordination framework and remarkable thermal expansion properties, which were significantly enhanced by inclusion of toluene.

INORGANIC CHEMISTRY (2021)

Add to Collection

Article Multidisciplinary Sciences

Understanding disorder and linker deficiency in porphyrinic zirconium-based metal-organic frameworks by resolving the Zr8O6 cluster conundrum in PCN-221

Charlotte Koschnick et al.

Summary: The study found that PCN-221 is composed of Zr6O4(OH)(4) clusters in four distinct orientations within the unit cell, rather than Zr8O6 clusters as originally published. A disordered PCN-224 model is proposed as a unified model to understand the relationships between different MOFs. This work introduces a new perspective on network topology and disorder in Zr-MOFs.

NATURE COMMUNICATIONS (2021)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Selected Negative Linear Compressibilities in the Metal-Organic Framework of [Cu(4,4′-bpy)2(H2O)2]•SiF6

Zhongwei Chen et al.

INORGANIC CHEMISTRY (2020)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Effect of H2O Molecules on Thermal Expansion of TiCo(CN)6

Qilong Gao et al.

INORGANIC CHEMISTRY (2020)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Synthesis and Defect Characterization of Phase-Pure Zr-MOFs Based on Meso-tetracarboxyphenylporphyrin

Shaunak M. Shaikh et al.

INORGANIC CHEMISTRY (2019)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Thermal expansion of ammonium pertechnetate and ammonium perrhenate

Emily M. Reynolds et al.

JOURNAL OF SOLID STATE CHEMISTRY (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Tuning the Negative Thermal Expansion Behavior of the Metal-Organic Framework Cu3BTC2 by Retrofitting

Christian Schneider et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Negative Thermal Expansion Design Strategies in a Diverse Series of Metal-Organic Frameworks

Nicholas C. Burtch et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

How to quantify isotropic negative thermal expansion: magnitude, range, or both?

Chloe S. Coates et al.

MATERIALS HORIZONS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Charge Order and Negative Thermal Expansion in V2OPO4

Elise Pachoud et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Add to Collection

Article Multidisciplinary Sciences

Continuous negative-to-positive tuning of thermal expansion achieved by controlled gas sorption in porous coordination frameworks

Josie E. Auckett et al.

NATURE COMMUNICATIONS (2018)

Add to Collection

Review Chemistry, Inorganic & Nuclear

When defects turn into virtues: The curious case of zirconium-based metal-organic frameworks

Marco Taddei

COORDINATION CHEMISTRY REVIEWS (2017)

Add to Collection

Review Chemistry, Multidisciplinary

Negative Poisson's Ratio in Modern Functional Materials

Chuanwei Huang et al.

ADVANCED MATERIALS (2016)

Add to Collection

Article Chemistry, Physical

Controlling Thermal Expansion: A Metal-Organic Frameworks Route

Salvador R. G. Balestra et al.

CHEMISTRY OF MATERIALS (2016)

Add to Collection

Article Chemistry, Physical

Porphyrinic Metal-Organic Framework Catalyzed Heck-Reaction: Fluorescence Turn-On Sensing of Cu(II) Ion

Yu-Zhen Chen et al.

CHEMISTRY OF MATERIALS (2016)

Add to Collection

Article Chemistry, Inorganic & Nuclear

The guest-dependent thermal response of the flexible MOF Zn-2(BDC)(2)(DABCO)

Yonghwi Kim et al.

DALTON TRANSACTIONS (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Structural Transitions of the Metal -Oxide Nodes within Metal- Organic Frameworks: On the Local Structures of NU-1000 and UiO-66

Ana E. Platero-Prats et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Framework-Topology-Dependent Catalytic Activity of Zirconium-Based (Porphinato)zinc(II) MOFs

Pravas Deria et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Add to Collection

Article Chemistry, Physical

Negative linear compressibility

Andrew B. Cairns et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2015)

Add to Collection

Article Chemistry, Multidisciplinary

Vapor-Phase Metalation by Atomic Layer Deposition in a Metal-Organic Framework

Joseph E. Mondloch et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Add to Collection

Article Chemistry, Multidisciplinary

Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts

Dawei Feng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Biomimetic Catalysis of a Porous Iron-Based Metal-Metalloporphyrin Framework

Yao Chen et al.

INORGANIC CHEMISTRY (2012)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal-Organic Frameworks

William Morris et al.

INORGANIC CHEMISTRY (2012)

Add to Collection

Article Chemistry, Physical

Elucidating Negative Thermal Expansion in MOF-5

Nina Lock et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2010)

Add to Collection

Article Chemistry, Multidisciplinary

Negative Thermal Expansion in the Metal-Organic Framework Material Cu-3(1,3,5-benzenetricarboxylate)(2)

Yue Wu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Add to Collection

© Peeref 2019-2024. All rights reserved.