Journal
MINERALS
Volume 12, Issue 8, Pages -Publisher
MDPI
DOI: 10.3390/min12080989
Keywords
White Tundra pegmatite; Pb-rich chevkinite-(Ce); CO2-bearing hydrothermal fluids; amorphous Pb-Ti-Fe-Si phase
Funding
- NCN Harmonia grant [2017/26/M/ST10/00407]
- RSCF [22-17-20002]
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An unusual hydrothermal alteration scheme for chevkinite-(Ce) from the White Tundra pegmatite was presented. The altered chevkinite-(Ce) gradually transformed into a Pb-Ti-Fe-Si phase with enrichment in lead and uranium. The acidic nature of the fluids led to the formation of bastnasite-(Ce) instead of cerussite.
An unusual hydrothermal alteration scheme was presented for chevkinite-(Ce) from the White Tundra pegmatite (2656 +/- 5 Ma), Keivy massif, Kola Peninsula. Pb-CO2-rich fluids initially removed REE and Y from the chevkinite-(Ce), with enrichment in Pb and U. PbO abundances reaching 17.35 wt%. Continued alteration resulted in the altered chevkinite-(Ce) being progressively transformed to a Pb-Ti-Fe-Si phase, which proved, upon EBSD analysis, to be almost totally amorphous. Pb enrichment was accompanied by a loss of LREE, especially La, relative to HREE, and the development of strong positive Ce anomalies. A notably U-rich aeschynite-(Y), with UO2 values <= 7.67 wt%, crystallized along with the chevkinite-(Ce). Aeschynite-(Y) with a lower UO2 value (3.91 wt%) and bastnasite-(Ce) formed during alteration. The formation of bastnasite-(Ce) rather than cerussite, which might have been expected in a high Pb-CO2 environment, is ascribed to the fluids being acidic.
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