Journal
CATALYSTS
Volume 12, Issue 8, Pages -Publisher
MDPI
DOI: 10.3390/catal12080821
Keywords
metal-free catalysis; environment-friendly processes; formation of C-C and C-Heteroatom bonds
Categories
Funding
- Shaanxi Province Key Research and Development Program [2019ZDLSF-03-03, 2021SF-115, 2021SF-366]
- National Natural Science Foundation of China [21272272]
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Developing a green, practical, and efficient method for the formation of C-C and C-Heteroatom bonds is crucial in modern organic synthetic chemistry. The I-2/DMSO catalytic system has attracted wide attention due to its green, high efficiency, low cost, and environmentally friendly properties. It has been successfully applied to the synthesis of various heteroatom-containing compounds, forming C-C and C-Heteroatom bonds efficiently.
Developing a green, practical and efficient method for the formation of C-C and C-Heteroatom bonds is an important topic in modern organic synthetic chemistry. In recent years, the I-2/DMSO catalytic system has attracted wide attention because of its green, high efficiency, atomic economy, low cost, mild reaction conditions and it is environment-friendly, which is more in line with the requirements of sustainable chemistry. Heteroatom-containing compounds have shown lots of important applications in pharmaceutical synthesis, agrochemicals, material chemistry and organic dyes. At present, the I-2/DMSO catalytic system has been successfully applied to the synthesis of various heteroatom-containing compounds. The C-C and C-Heteroatom bonds have been formed efficiently, which has been proved to be a green and mild catalytic system. In this review, the research achievements of the I-2/DMSO catalytic system in the formation of C-C and C-Heteroatom bonds from 2015 to date are described, and the research area is prospected. This review attempts to reveal the general law of iodine catalysis and lay a foundation for the design of new reactions.
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