4.5 Article

Nano-Kirigami Structures and Branched Nanowires Fabricated by Focused Ion Beam-Induced Milling, Bending, and Deposition

Journal

ADVANCED MATERIALS INTERFACES
Volume 9, Issue 28, Pages -

Publisher

WILEY
DOI: 10.1002/admi.202200696

Keywords

branched nanowires; focused ion beam; focused ion beam-induced deposition; helium ion microscopy; Ion beam-induced bending; kirigami; neon focused ion beam

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3D nanostructures are crucial for creating custom devices with unique functionalities. This study presents a method using ion beams to induce bending and folding in membranes, resulting in the formation of nano-kirigamis with controlled angles and directions. The approach involves milling 2D patterns into the membrane using helium or neon ion beams, followed by broad and uniform irradiation using gallium ion beams to induce out-of-plane bending. This technique allows for the fabrication of complex 3D nanostructures and branched nanowires.
3D nanostructures hold the key to building custom devices with special and flexible functionalities. Ion beam-induced bending and folding are used for the fabrication of 3D nanostructures from prepared 2D nano-patterned membranes. Tensile and compressive stresses can be introduced within the layers of a thin membrane under ion beam irradiation to manipulate and control the formation of nano-kirigamis. Both localized and broader ion beam irradiation can be used to induce bending in the membrane with remarkable control of the bending angle and direction. In this work, an approach to fabricate nano-kirigamis with focused ion beams (FIBs) is developed. First, helium or neon ion beams are used to mill 2D patterns into the planar membrane with good accuracy, nanoscale, and less damage. Subsequently, gallium ion beam is used to broadly and uniformly irradiate the patterned region to induce out-of-plane bending to form nano-kirigamis. Both upward and downward bending are observed for different thicknesses of membranes. The bending angle is easily controlled by varying the irradiation dosage. Moreover, with FIB-induced deposition, nanopillars, or nanowires (NWs) can be grown on the membrane before or after bending. Various complex 3D nanostructures and branched NWs can be fabricated using this approach.

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