Journal
CHEMISTRYOPEN
Volume 11, Issue 9, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/open.202200135
Keywords
acrylic acid; carbohydrate; lipase; novozym 435; supported ionic liquid phase
Categories
Funding
- NFDI4Cat (DFG) [441926934]
- Leibniz Association
- Leibniz Science Campus ComBioCat
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A series of novel glucose-based ionic liquids were synthesized in high yields using simple reaction procedures. These ionic liquids were compared to commercially available imidazolium-based ionic liquids as supports for Novozym 435 in the acrylation of n-butanol. It was found that the availability of hydroxy groups in the glucose-based ionic liquids correlated directly with the overall activity and enhanced recyclability of the biocatalyst.
A series of novel ionic liquids based on glucose was synthesized in high yields in simple two or three-step reaction procedures. These carbohydrate-based ionic liquids were studied and compared to commercially available imidazolium-based ionic liquids as supports for Novozym 435 in the acrylation of n-butanol. A direct correlation between the availability of hydroxy groups and the overall activity as well as an enhanced recyclability of the biocatalyst has been found for the glucose-based ionic liquids.
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