4.7 Article

Viscoelastic Behavior and Phase Structure of High-Content SBS-Modified Asphalt

Journal

POLYMERS
Volume 14, Issue 12, Pages -

Publisher

MDPI
DOI: 10.3390/polym14122476

Keywords

high-content polymer modified asphalt; SBS; viscoelastic behavior; phase structure

Funding

  1. National Natural Science Foundation of China [52122809, 52038001]
  2. Fok Ying-Tong Education Foundation [161072]
  3. Youth Top-notch Talent Support Program of Shaanxi Province
  4. Fundamental Research Funds for the Central Universities-Excellent doctoral cultivation project of Chang'an University [300203211215]
  5. China Scholarship Council (CSC) [202006560054]

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This study investigated the effect of styrene-butadiene-styrene (SBS) modifier content on the viscoelastic behavior of SBS-modified asphalt (SBSMA) at different temperatures and phase structures. The results showed that there was an apparent turning point at 4.5% content at high temperatures. The fatigue life of SBSMA increased exponentially with the rising modifier content at medium temperatures. At low temperatures, the low-temperature viscoelastic property index of SBSMA decreased logarithmically as the modifier content increased. Microscopic analysis revealed that the SBS modifier changed from dispersed to continuous phase state with increasing content.
To investigate the effect of styrene-butadiene-styrene (SBS) modifier content on the viscoelastic behavior of SBS-modified asphalt (SBSMA) at different temperatures and phase structures, the star SBS modifier was chosen to fabricate seven types of SBSMA with different contents. Multiple stress creep recovery (MSCR), linear amplitude sweep (LAS), and low-temperature frequency sweep tests were adopted to study the influence of SBS modifier content on the viscoelastic performance of SBSMA at high to low temperatures. The SBSMA's microstructure with different contents was investigated using a fluorescence microscope. The results indicated that the change in non-recoverable creep compliance and creep recovery rate was bounded by 4.5% content at high temperatures, with an apparent turning point. The changing slope of content at less than 4.5% was much higher than that of the content greater than 4.5%. At medium temperatures, the fatigue life of SBSMA increased exponentially with the rising modifier content. The rate of increase in fatigue life was the largest as the content increased from 4.5% to 6.0%. At low temperatures, the low-temperature viscoelastic property index G (60 s) of SBSMA decreased logarithmically as the modifier content increased. In terms of the microscopic phase structure, the SBS modifier gradually changed from the dispersed to the continuous phase state with the increasing SBS modifier content.

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