4.7 Article

Preparation and Recognition Properties of Molecularly Imprinted Nanofiber Membrane of Chrysin

Journal

POLYMERS
Volume 14, Issue 12, Pages -

Publisher

MDPI
DOI: 10.3390/polym14122398

Keywords

chrysin; electrospinning; molecular imprinting membrane; adsorption

Funding

  1. National Natural Science Foundation of China [31860192]
  2. Natural Science Foundation of Guangxi [2020GXNSFBA159009]
  3. China Postdoctoral Science Foundation [2020M683209]
  4. Opening Project of Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control [2019KF28]
  5. Scientific Research Foundation of Guangxi Minzu University [2019KJQD10]
  6. Xiangsihu Young Scholars Innovative Research Team of Guangxi Minzu University [2021RSCXSHQN01]

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A molecularly imprinted nanofiber membrane (MINM) with good adsorption performance for chrysin was prepared using electrospinning, showing potential for the adsorption and separation of active components in natural products.
The separation and extraction of chrysin from active ingredients of natural products are of great significance, but the existing separation and extraction methods have certain drawbacks. Here, chrysin molecularly imprinted nanofiber membranes (MINMs) were prepared by means of electrospinning using chrysin as a template and polyvinyl alcohol and natural renewable resource rosin ester as membrane materials, which were used for the separation of active components in the natural product. The MINM was examined using Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The adsorption performance, adsorption kinetics, adsorption selectivity, and reusability of the MINM were investigated in static adsorption experiments. The analysis results show that the MINM was successfully prepared with good morphology and thermal stability. The MINM has a good adsorption capacity for chrysin, showing fast adsorption kinetics, and the maximum adsorption capacity was 127.5 mg center dot g(-1), conforming to the Langmuir isotherm model and pseudo-second-order kinetic model. In addition, the MINM exhibited good selectivity and excellent reusability. Therefore, the MINM proposed in this paper is a promising material for the adsorption and separation of chrysin.

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