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Fast-Charging Strategies for Lithium-Ion Batteries: Advances and Perspectives

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Rate Performance of LiCoO2 Half-cells Using Highly Concentrated Lithium Bis(fluorosulfonyl)amide Electrolytes and Their Relevance to Transport Properties

Shinji Kondou et al.

Summary: The study suggests that electrolytes with high transference number (t(+)) can improve the mass transfer of Li+ ions, leading to higher discharge capacities in batteries. The GBL-based electrolyte demonstrated better rate performance at high current densities compared to DMC- and DME-based electrolytes. The importance of t(Li+)(current) on the rate capability of LCO half-cells with highly concentrated electrolytes for high-rate battery performance was highlighted.

ELECTROCHEMISTRY (2021)

Article Chemistry, Physical

Directional LiFePO4 cathode structure by freeze tape casting to improve lithium ion diffusion kinetics

Yongming Guo et al.

Summary: Batteries with fast recharge rates and sufficient capacity are important for applications like electric transportation and renewable energy storage. Designing an electrode structure that facilitates the transport of lithium ions and electrons can help improve capacity retention during fast charging and discharging. LiFePO4 cathodes with directional microstructures were studied, and an optimized electrode with competitive discharge capacities was obtained. The scalability of the freeze tape casting technique was demonstrated with a relatively large cathode.

JOURNAL OF POWER SOURCES (2021)

Article Chemistry, Physical

Analysis and detection of lithium deposition after fast charging of lithium-ion batteries by investigating the impedance relaxation

Felix Katzer et al.

Summary: The article introduces an in-situ detection method for detecting lithium deposition, which analyzes battery behavior for LD detection and adjusts charging rate based on detection results. Multiple methods are employed to detect LD, including coulombic efficiency, dilation method, differential voltage analysis, and impedance relaxation method. Characteristic frequencies are identified using impedance spectroscopy for mechanistic interpretation of the phenomena.

JOURNAL OF POWER SOURCES (2021)

Article Electrochemistry

Operando Measurements of Electrolyte Li-ion Concentration during fast charging with FTIR/ATR

Lydia Meyer et al.

Summary: Research focused on ion transport for fast charging of Li-ion batteries using FTIR/ATR for in-situ measurements. Changes in lithium concentration were observed to increase with increasing C-rate, and lithium concentration changes could be observed using GITT testing.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2021)

Article Multidisciplinary Sciences

Twin boundary defect engineering improves lithium-ion diffusion for fast-charging spinel cathode materials

Rui Wang et al.

Summary: Introducing twin boundaries into spinel cathodes facilitates fast lithium ion diffusion, leading to excellent fast charging performance, as demonstrated through detailed structural analysis and electrochemical experiments.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Physical

A Multifunctional Dual-Salt Localized High-Concentration Electrolyte for Fast Dynamic High-Voltage Lithium Battery in Wide Temperature Range

Shuangshuang Lin et al.

Summary: This study introduces a multifunctional high-concentration electrolyte containing fluorocarbonate, which shows excellent performance under high voltage and low temperature conditions, providing a new approach for designing high-performance lithium batteries.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Multidisciplinary

Identifying the Association between Surface Heterogeneity and Electrochemical Properties in Graphite

Jaewon Kim et al.

Summary: Graphite materials for commercial Li-ion batteries are treated to control specific parameters for desirable electrochemical properties. The surface of graphite can be divided into basal and edge planes, with defect sites affecting the formation of the solid-electrolyte interphase (SEI).

NANOMATERIALS (2021)

Article Chemistry, Multidisciplinary

Structural Evolution and Transition Dynamics in Lithium Ion Battery under Fast Charging: An Operando Neutron Diffraction Investigation

Xianyang Wu et al.

Summary: This study investigates the structural evolution of Ni-rich LiNi0.6Mn0.2Co0.2O2 (NMC622) and graphite electrodes under different charging rates, revealing that NMC622 exhibits consistent structural changes regardless of the charging rate while the phase transitions of LixC6 are affected by the charging rate. The transition from stage II (LiC12) to stage I (LiC6) is identified as the rate-limiting step during fast charging, which is concluded as a diffusion-controlled, 1D phase transition with decreasing nucleation kinetics under increasing charging rates.

ADVANCED SCIENCE (2021)

Review Chemistry, Physical

Interphase Engineering by Electrolyte Additives for Lithium-Rich Layered Oxides: Advances and Perspectives

Jingteng Zhao et al.

Summary: This review paper summarizes the research progress in functional electrolyte additives for LLOs, discusses the mechanisms of CEI construction, and tentatively proposes suggestions to promote the large-scale application of LLOs for LIBs through screening and customizing electrolyte additives.

ACS ENERGY LETTERS (2021)

Article Chemistry, Physical

Fast-Charging Aging Considerations: Incorporation and Alignment of Cell Design and Material Degradation Pathways

Parameswara R. Chinnam et al.

Summary: Fast charging of electric vehicle batteries is crucial for increasing adoption rates, but is limited by battery aging. Research has shown that even slight variations in battery design and charging protocols can have significant impacts on battery aging, with as little as 2% change in porosity affecting aging pathways.

ACS APPLIED ENERGY MATERIALS (2021)

Article Chemistry, Physical

Enhancing rate capability of graphite anodes for lithium-ion batteries by pore-structuring

Daeun Jang et al.

Summary: In this study, pore-structured graphite electrodes were synthesized using a pore-formation agent, resulting in improved fast charging capability after heat treatment. The 3-dimensionalized electrode structure enhanced rate capability and cycle life by improving wetting ability and shortening ionic diffusion pathways. This cost-effective approach does not require changes in existing electrode chemistry or slurry process.

APPLIED SURFACE SCIENCE ADVANCES (2021)

Article Electrochemistry

Influence of Temperature and Electrolyte Composition on the Performance of Lithium Metal Anodes

Sanaz Momeni Boroujeni et al.

Summary: This study investigated the behavior of lithium metal anode under different temperature, lithium salts, electrolyte concentrations, and cell currents, finding that cells at moderate temperature exhibit the highest efficiency, while high temperature results in the worst performance. Higher C-rates have a positive impact on the stability of lithium cells over cycling life.

BATTERIES-BASEL (2021)

Article Chemistry, Multidisciplinary

Ultrafine-grained Ni-rich layered cathode for advanced Li-ion batteries

Geon-Tae Park et al.

Summary: Limiting the primary particle size of cathodes can effectively address capacity fading issues and improve battery cycling stability. The introduction of Mo helps inhibit primary particle growth, leading to enhanced cycle life for Li[Ni0.95Co0.04Mo0.01]O-2.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Article Chemistry, Multidisciplinary

Pathways towards managing cost and degradation risk of fast charging cells with electrical and thermal controls

Juhyun Song et al.

Summary: The study shows that by introducing a constant-risk fast charging protocol under moderate allowable risks of degradation, an 80% charging of a typical NMC/graphite cell can be achieved in just 10 minutes at a low cost.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Article Chemistry, Physical

Operando video microscopy of Li plating and re-intercalation on graphite anodes during fast charging

Yuxin Chen et al.

Summary: This study used plan-view operando video microscopy to investigate lithium plating on graphite anodes in high-energy-density batteries. The results show that lithium plating mainly occurs on graphite particles and is correlated with local minimum of graphite electrode potential. Galvanic corrosion currents are responsible for lithium re-intercalation and dead lithium formation.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Chemistry, Physical

Preventing lithium plating under extremes: an untold tale of two electrodes

Amy Bohinsky et al.

Summary: The study demonstrates the role of cathode-induced cell failure even when anode-centric lithium plating is prevented, and proposes pathways for future BMS algorithm development to enable Li-ion cells to operate under extremes. Operating the cell in conditions favorable to the anode may lead to cathode degradation and subsequent cell failure, indicating the importance of balanced electrode potential control.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Electrochemistry

Composition-Dependent Long-Term Stability of Mosaic Solid-Electrolyte Interface for Long-Life Lithium-Ion Battery

Vallabha Rao Rikka et al.

Summary: The solid-electrolyte interface (SEI) layer plays a crucial role in determining the fast charging capability and cycle life of lithium-ion batteries, especially during high-rate cycling. The composition and stability of the SEI layer are essential for preventing SEI breakdown and growth, ultimately extending the battery's cycle life. The density of the SEI layer increases during cycling due to the decomposition of entrapped electrolyte, leading to new possibilities for enhancing lithium-ion battery performance.

BATTERIES & SUPERCAPS (2021)

Article Chemistry, Physical

Rate dependent structural changes, cycling stability, and Li-ion diffusivity in a layered-layered oxide cathode material after prolonged cycling

Songyoot Kaewmala et al.

Summary: Li-Rich layered oxide (LLO) cathode materials are considered promising for large scale applications due to their high specific capacities. In electric vehicles, electrode materials with high energy density and rate capability are required. The cycling rate affects the activation, structure, and Li-ion diffusion of materials, significantly impacting their cycling stability.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Electrochemistry

Implication of Non-Uniform Anode Particle Morphology on Lithium-Ion Cell Performance

Brajesh Kumar Kanchan et al.

Summary: The study highlights the significant improvement in the performance of Lithium-ion battery with non-uniform particle distribution, especially during ultra-fast charging. Additionally, the capacity and specific power of the cell are found to be maximum when particle size decreases along the electrode length.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2021)

Article Chemistry, Physical

Understanding extreme fast charge limitations in carbonate mixtures

Anudeep Mallarapu et al.

Summary: This study focuses on the impact of changing electrolyte composition on the performance of lithium-ion batteries under extreme fast charging conditions. Molecular dynamics studies were conducted to estimate transport properties at different salt concentrations, and molecular-level differences in solvent structure under extreme LiPF6 concentrations were explored, highlighting key aspects that help overcome barriers to Li+ transport during extreme fast charging.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Electrochemistry

Insights Into Thermal Runaway of Li-Ion Cells by Accelerating Rate Calorimetry Coupled with External Sensors and Online Gas Analysis

Abdelaziz A. Abd-EI-Latif et al.

Summary: This paper explores the safety of Li-ion batteries by studying the behavior of aged and overcharged cells, finding that they exhibit early onset of self-heating compared to unaged cells. The novel ARC-MS setup used in the study allows for tracking both electrochemical and thermal behavior simultaneously.

BATTERIES & SUPERCAPS (2021)

Article Energy & Fuels

The Influence of Structure on the Electrochemical and Thermal Response of Li-Ion Battery Electrodes

Prehit Patel et al.

JOURNAL OF ENERGY RESOURCES TECHNOLOGY-TRANSACTIONS OF THE ASME (2020)

Article Chemistry, Physical

Unraveling the Rapid Redox Behavior of Li-Excess 3d-Transition Metal Oxides for High Rate Capability

Wooyoung Jin et al.

ADVANCED ENERGY MATERIALS (2020)

Article Engineering, Chemical

Effects of charging rates on LiNi0.6Mn0.2Co0.2O2 (NMC622)/graphite Li-ion cells

Xianyang Wu et al.

Journal of Energy Chemistry (2020)

Article Electrochemistry

Improved Capacity Retention of Lithium Ion Batteries under Fast Charge via Metal-Coated Graphite Electrodes

Killian R. Tallman et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2020)

Review Chemistry, Multidisciplinary

A review on energy chemistry of fast-charging anodes

Wenlong Cai et al.

CHEMICAL SOCIETY REVIEWS (2020)

Article Chemistry, Physical

Electrokinetic Phenomena Enhanced Lithium-Ion Transport in Leaky Film for Stable Lithium Metal Anodes

Guoxing Li et al.

ADVANCED ENERGY MATERIALS (2019)

Article Electrochemistry

Enabling fast charging of high energy density Li-ion cells with high lithium ion transport electrolytes

Zhijia Du et al.

ELECTROCHEMISTRY COMMUNICATIONS (2019)

Review Chemistry, Physical

Commercialization of Lithium Battery Technologies for Electric Vehicles

Xiaoqiao Zeng et al.

ADVANCED ENERGY MATERIALS (2019)

Review Energy & Fuels

Lithium-ion battery fast charging: A review

Anna Tomaszewska et al.

ETRANSPORTATION (2019)

Article Multidisciplinary Sciences

Fast charging of lithium-ion batteries at all temperatures

Xiao-Guang Yang et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2018)

Review Energy & Fuels

Batteries and fuel cells for emerging electric vehicle markets

Zachary P. Cano et al.

NATURE ENERGY (2018)

Article Multidisciplinary Sciences

Molecular Dynamics of Lithium Ion Transport in a Model Solid Electrolyte Interphase

Ajay Muralidharan et al.

SCIENTIFIC REPORTS (2018)

Article Electrochemistry

Identifying the limiting electrode in lithium ion batteries for extreme fast charging

Chengyu Mao et al.

ELECTROCHEMISTRY COMMUNICATIONS (2018)

Article Chemistry, Multidisciplinary

How Solid-Electrolyte Interphase Forms in Aqueous Electrolytes

Liumin Suo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Unusual Stability of Acetonitrile-Based Superconcentrated Electrolytes for Fast-Charging Lithium-Ion Batteries

Yuki Yamada et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)