4.6 Article

Preparation and Microstructure of Alkali-Activated Rice Husk Ash-Granulated Blast Furnace Slag Tailing Composite Cemented Paste Backfill

Journal

MATERIALS
Volume 15, Issue 13, Pages -

Publisher

MDPI
DOI: 10.3390/ma15134397

Keywords

alkali excitation rice husk ash; GGBS composite cementitious material; strength formation mechanism; microstructure; filling

Funding

  1. National Natural Science Foundation of China [52074144]
  2. Natural Science Foundation of Liaoning Province [2019-MS-158]
  3. Liaoning Provincial Education Department [LJ2020JCL001]
  4. Discipline Innovation Team of Liaoning Technical University [LNTU20TD-12]

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The study investigates the application of rice hull ash and cement-based materials as cementitious materials. The results show that an appropriate amount of rice hull ash can improve the strength of the material and make the internal structure denser. Rice hull ash has a high specific surface area and a high content of active silica, which is of importance in material research.
At present, the research on rice hull ash and cement-based materials as cementitious materials continues to deepen. Low-cost rice hull ash replaces part of Portland cement, which plays a dual role in saving material costs and improving environmental benefits. In this study, alkali-activated rice husk ash (RHA) and ground granulated blast furnace slag (GGBS) were used to prepare cementitious material. The influence of RHA dosage on the strength, slump degree, and coagulation time of cementitious material was studied. On this basis, tailing was used as an aggregate based on the orthogonal design method and the bone-gel ratio, modulus, and alkali content were taken as variable factors, with strength and slump degree taken as the targets. A new cemented paste backfill (CPB) was prepared and mix ratio optimization was carried out. The strength formation mechanism of cementitious material and CPB was explored by combining scanning electron microscopy (SEM), energy dispersive spectrometry (EDS) and X-ray diffraction (XRD). The results of this study show that with the increase in RHA mixing, the unconfined compressive strength (UCS) of the gelling material purification slurry showed a tendency first to increase and then decrease. When the amount of RHA was about 10%, the internal structure became denser, more C-S-H gel was generated, and greater strength could be obtained. The specific surface area of RHA is high, and a small amount of RHA can fill the internal pores, making the internal structure of concrete more dense. The active silica content in RHA is relatively high. The addition of RHA can appropriately improve the strength of the material, which is of certain significance to our material research. Finally, the micro-analysis of RHA-GGBS clean slurry, the analysis of influencing factors of fluidity and strength, and the optimal mix proportion of alkali-activated RHA-GGBS-based backfill are put forward.

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