4.6 Article

Tribological Behavior of Reduced Graphene Oxide-Al2O3 Nanofluid: Interaction among Testing Force, Rotational Speed and Nanoparticle Concentration

Journal

MATERIALS
Volume 15, Issue 15, Pages -

Publisher

MDPI
DOI: 10.3390/ma15155177

Keywords

reduced graphene oxide; tribology; nanofluid; lubrication mechanism; response surface methodology

Funding

  1. National Natural Science Foundation of China [51874036]
  2. Natural Science Foundation of Henan Province [202300410543]
  3. Fundamental Research Funds for the Central Nonprofit Research Institutions [HKY-JBYW-2020-08]
  4. Open Research Subject of Research Center on Levee Safety Disaster Prevention, Ministry ofWater Resources [LSDP202108]

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By studying the tribological behavior of reduced graphene oxide-Al2O3 nanofluid, it was found that 0.20% mass concentration showed excellent lubrication performance, and the optimized response values were obtained through analysis. Tribochemical reactions occurred during the friction process, generating a tribofilm with self-lubrication properties.
The tribological properties of nanofluids are influenced by multiple factors, and the interrelationships among the factors are deserving of further attention. In this paper, response surface methodology (RSM) was used to study the tribological behavior of reduced graphene oxide-Al2O3 (rGO-Al2O3) nanofluid. The interaction effects of testing force, rotational speed and nanoparticle concentration on the friction coefficient (mu), wear rate (W-r) and surface roughness (R-a) of steel disks were investigated via the analysis of variance. It was confirmed that all the three input variables were significant for mu and W-r values, while testing force, nanoparticle concentration and its interaction with testing force and rotational speed were identified as significant parameters for R-a value. According to regression quadratic models, the optimized response values were 0.088, 2.35 x 10(-7) mm(3)center dot N-1 center dot m(-1) and 0.832 mu m for mu, W-r and R-a, which were in good agreement with the actual validation experiment values. The tribological results show that 0.20% was the optimum mass concentration which exhibited excellent lubrication performance. Compared to the base fluid, mu, W-r and R-a values had a reduction of approximately 45.6%, 90.3% and 56.0%. Tribochemical reactions occurred during the friction process, and a tribofilm with a thickness of approximately 20 nm was generated on the worn surface, consisting of nanoparticle fragments (rGO and Al2O3) and metal oxides (Fe2O3 and FeO) with self-lubrication properties.

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