Effect of Bimetallic-Activated Carbon Impregnation on Adsorption-Desorption Performance for Hydrogen Sulfide (H2S) Capture

This study reports on the impregnation of bi-metallic adsorbents based on commercial coconut activated carbon (CAC), surface-modified with metal acetate (ZnAc2), metal oxide (ZnO and TiO2), and the basic compound potassium hydroxide (KOH). The morphology of the adsorbents was then characterized with SEM-EDX, the microporosity was determined using Brunauer-Emmett-Teller (BET) analysis, the thermal stability was investigated via thermogravity analysis (TGA), and functional group analysis was undertaken with Fourier-transform infrared (FTIR) spectroscopy. These modified adsorbents were subjected to a real adsorption test for H2S capture using a 1 L adsorber with 5000 ppm H2S balanced for N-2, with temperature and pressure maintained at an ambient condition. Adsorption-desorption was carried out in three cycles with the blower temperature varied from 50 degrees C to 150 degrees C as the desorption condition. Characterization results revealed that the impregnated solution homogeneously covered the adsorbent surface, effecting the morphology and properties. Based on this study, it was found that ZnAc2/TiO2/CAC_DCM showed a significant increase in adsorption capacity with the different temperatures applied for the desorption in the second cycle: 1.67 mg H2S/g at 50 degrees C, 1.84 mg H2S/g at 100 degrees C, and 1.96 mg H2S/g at 150 degrees C. ZnAc2/ZnO/CAC_DCM seemed to produce the lowest percentage of degradation in the three cycles for all the temperatures used in the adsorption-desorption process. Therefore, ZnAc2/ZnO/CAC_DCM has the potential to be used and commercialized for biogas purification for H2S removal.

Automated summary

This study investigates the impregnation of bi-metallic adsorbents on commercial coconut activated carbon and their potential for biogas purification. The modified adsorbents were characterized and tested for H2S capture. The results showed that ZnAc2/TiO2/CAC_DCM exhibited increased adsorption capacity, while ZnAc2/ZnO/CAC_DCM had the lowest degradation percentage.