Bridging Plastic Recycling and Organic Catalysis: Photocatalytic Deconstruction of Polystyrene via a C-H Oxidation Pathway

Chemical recycling of synthetic polymers represents a promising strategy to deconstruct plastic waste and make valuable products. Inspired by small-molecule C-H bond activation, a visible-light-driven reaction is developed to deconstruct polystyrene (PS) into , similar to 40% benzoic acid as well as similar to 20% other monomeric aromatic products at 50 degrees C and ambient pressure. The practicality of this strategy is demonstrated by deconstruction of real-world PS foam on a gram scale. The reaction is proposed to proceed via a C-H bond oxidation pathway, which is supported by theoretical calculations and experimental results. Fluorescence quenching experiments also support efficient electron transfer between the photocatalyst and the polymer substrate, providing further evidence for the proposed mechanism. This study introduces concepts from small-molecule catalysis to polymer deconstruction and provides a promising method to tackle the global crisis of plastic pollution.

Automated summary

Chemical recycling of synthetic polymers is a promising strategy to deconstruct plastic waste and produce valuable products. In this study, a visible-light-driven reaction was developed to deconstruct polystyrene (PS) into benzoic acid and other aromatic products, and the practicality of this strategy was demonstrated by deconstructing PS foam on a gram scale. The reaction proceeded via a C-H bond oxidation pathway, which was supported by theoretical calculations and experimental results. The study introduces concepts from small-molecule catalysis to polymer deconstruction and provides a promising method to address the global crisis of plastic pollution.