Journal
ACS CATALYSIS
Volume 12, Issue 15, Pages 9430-9436Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.2c02785
Keywords
alkyl − alkyl cross -coupling; transition metals; metal tuning; k; Cross
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Funding
- University of Minnesota
- Petroleum Research Fund of the American Chemical Society [ACS PRF 62432-DNI1]
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This study investigates the mechanism of a transformation reaction catalyzed by early transition metals. It identifies an ideal Y catalyst through metal tuning to optimize the oxidation potential, which governs the rate-limiting step. A wide substrate scope, including various functional groups and less activated substrates, is revealed.
transformation typically catalyzed by late transition metals. Herein, we report a mechanistic investigation into an early transition metal-catalyzed variant of this reaction. Through this mechanistic understanding, an ideal Y catalyst was determined through tuning of the metal in order to optimize the oxidation potential, which governs the rate-limiting step in this reaction. A wide substrate scope is revealed that includes a variety of functional groups as well as less activated substrates.
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