4.7 Article

Design and preparation of Al-Fe-Ce ternary aluminum alloys with high thermal conductivity

Journal

TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
Volume 32, Issue 6, Pages 1781-1794

Publisher

ELSEVIER
DOI: 10.1016/S1003-6326(22)65908-9

Keywords

Al-Fe-Ce alloys; Ce modification; thermal conductivity; mechanical properties

Funding

  1. National Natural Science Foundation of China [52174363]
  2. GDAS Project of Science and Technology Development, China [2019GDASYL-0203002]
  3. Key Research and Development Program of Guangdong Province, China [2020B010186002]
  4. Science and Technology Project of Zhaoqing City, China [2021C003, 2018K006]
  5. Development of Key Technologies for Material and Microstructure Control of High Thermal Conductivity Casting Aluminum Alloy, China [2014A030313221]

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The addition of Ce element improved the crystallization and conductivity properties of Al-2%Fe alloy, as well as its mechanical performance.
Ce element was introduced to modify Al-2%Fe (mass fraction) binary alloy. The microstructures, crystallization behavior, electrical/thermal conductivities and mechanical properties of these alloys were systematically investigated. The results indicated that the appropriate Ce addition decreased the recalescence temperature and growth temperature of Al-Fe eutectic structure, improved the morphology and distribution of Fe-containing phase, and simultaneously increased the conductivity and mechanical properties. The annealed treatment improved the thermal conductivity of these alloys due to the decreasing concentration of point defects. Rolling process further broke up the coarser Fe-containing phases into finer particles and made the secondary phases uniformly distributed in the alpha(Al) matrix. After subsequent annealing treatment and rolling deformation, the thermal conductivity, ultimate tensile strength and hardness of the Al-2%Fe-0.3%Ce (mass fraction) alloy reached 226 W/(m center dot K), (182 +/- 1.4) MPa and HBW (49.5 +/- 1.7), respectively.

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