☆ 4.5 Review

Recent Metal-Catalyzed Methods for Thioether Synthesis

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Cp*Rh(III)-Catalyzed Regioselective C(sp3)-H Electrophilic Trifluoromethylthiolation of 8-Methylquinolines

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CHEMISTRY-A EUROPEAN JOURNAL (2018)

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Theoretical investigation of the impact of ligands on the regiodivergent Rh-catalyzed hydrothiolation of allyl amines

Lingli Han et al.

DALTON TRANSACTIONS (2018)

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Palladium-Catalyzed Oxidative Cross-Coupling of Arylhydrazines and Arenethiols with Molecular Oxygen as the Sole Oxidant

Changliu Wang et al.

JOURNAL OF ORGANIC CHEMISTRY (2018)

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Palladium-Catalyzed Cyanothiolation of Internal Alkynes Using Organic Disulfides and tert-Butyl Isocyanide

Shinya Higashimae et al.

JOURNAL OF ORGANIC CHEMISTRY (2018)

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Lewis Acid/Bronsted Acid Controlled Pd(II)-Catalyzed Chemodivergent Functionalization of C(sp2)-H Bonds with N-(Arylthio)i(a)mides

Manthena Chaitanya et al.

ORGANIC LETTERS (2018)

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General Synthesis of Alkenyl Sulfides by Palladium-Catalyzed Thioetherification of Alkenyl Halides and Tosylates

Noelia Velasco et al.

ORGANIC LETTERS (2018)

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Ruthenium-catalyzed decarboxylative C-S cross-coupling of carbonothioate: synthesis of allyl(aryl)sulfide

Ren-Hua Zheng et al.

RSC ADVANCES (2018)

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Copper-catalyzed peri-selective direct sulfenylation of 1-naphthylamines with disulfides

Yan-Shi Xiong et al.

ORGANIC CHEMISTRY FRONTIERS (2018)

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A thiol-free synthesis of alkynyl chalcogenides by the copper-catalyzed C-X (X = S, Se) cross-coupling of alkynyl carboxylic acids with Bunte salts

Fanmin Liu et al.

ORGANIC CHEMISTRY FRONTIERS (2018)

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Review Chemistry, Multidisciplinary

Analysis of US FDA-Approved Drugs Containing Sulfur Atoms

Kevin A. Scott et al.

TOPICS IN CURRENT CHEMISTRY (2018)

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Palladium-Catalyzed Regioselective Three-Component Cascade Bisthiolation of Terminal Alkynes

Jianxiao Li et al.

ADVANCED SYNTHESIS & CATALYSIS (2018)

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Ex Situ Formation of Methanethiol: Application in the Gold(I)-Promoted Anti-Markovnikov Hydrothiolation of Olefins

Steffan K. Kristensen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Catalytic Hydrothiolation: Regio- and Enantioselective Coupling of Thiols and Dienes

Xiao-Hui Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Article Chemistry, Organic

Highly Regioselective Rh-III-Catalyzed Thiolation of N-Tosyl Acrylamides: General Access to (Z)-beta-Alkenyl Sulfides

Can Liu et al.

ORGANIC LETTERS (2018)

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Article Chemistry, Organic

C-S cross-coupling reactions catalyzed by a non-symmetric phosphinito-thiophosphinito PSCOP-Ni(II) pincer complex

Juan M. Serrano-Becerra et al.

TETRAHEDRON LETTERS (2018)

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Article Chemistry, Organic

Synthesis of Functionalized Diaryl Sulfides by Cobalt-Catalyzed Coupling between Arylzinc Pivalates and Diaryl Disulfides

Zhi-Bing Dong et al.

ORGANIC LETTERS (2018)

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A Hemilabile and Cooperative N-Donor-Functionalized 1,2,3-Triazol-5-Ylidene Ligand for Alkyne Hydrothiolation Reactions

Ian Strydom et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

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Palladium-Catalyzed Migratory Insertion of Isocyanides into C(thiophene)-SMe Bonds: Access to Atom-Transfer Reactions

Amir Hossein Vahabi et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2017)

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Nickel-Catalyzed C-S Coupling: Synthesis of Diaryl Sulfides Starting from Phenyldithiocarbamates and Iodobenzenes

Xing Liu et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2017)

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Rh(III)-Catalyzed Direct ortho-Chalcogenation of Phenols and Anilines

Shiping Yang et al.

JOURNAL OF ORGANIC CHEMISTRY (2017)

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Scope and Mechanism of Iridium Porphyrin-Catalyzed S-H Insertion Reactions between Thiols and Diazo Esters

Taiwo O. Dairo et al.

ORGANOMETALLICS (2017)

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Palladium-catalyzed carbon-sulfur or carbon-phosphorus bond metathesis by reversible arylation

Zhong Lian et al.

SCIENCE (2017)

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When Weaker Can Be Tougher: The Role of Oxidation State (I) in P-vs N-Ligand-Derived Ni-Catalyzed Trifluoromethylthiolation of Aryl Halides

Indrek Kalvet et al.

ACS CATALYSIS (2017)

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Para-Selective C-H Thioetherification

Wei-Chieh Hsu et al.

ASIAN JOURNAL OF ORGANIC CHEMISTRY (2017)

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Regiocontrolled direct C4 and C2-methyl thiolation of indoles under rhodium-catalyzed mild conditions

Saurabh Maity et al.

CHEMICAL COMMUNICATIONS (2017)

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Rhodium-catalyzed odorless synthesis of diaryl sulfides from borylarenes and S-aryl thiosulfonates

Kazuya Kanemoto et al.

CHEMICAL COMMUNICATIONS (2017)

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Article Chemistry, Applied

Copper(I)-Catalyzed Alkyl- and Arylsulfenylation of 3,4-Dihalo-2(5H)-furanones (X= Br, Cl) with Sulfoxides under Mild Conditions

Liang Cao et al.

ADVANCED SYNTHESIS & CATALYSIS (2017)

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Sulfur-directed carbon-sulfur bond cleavage for Rh-catalyzed regioselective alkynylthiolation of alkynes

Takanori Shibata et al.

CHEMICAL COMMUNICATIONS (2017)

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CuI/Oxalic Diamide-Catalyzed Cross-Coupling of Thiols with Aryl Bromides and Chloridess

Chia-Wei Chen et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

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Sustainable metal catalysis in C-H activation

Nikolaos V. Tzouras et al.

COORDINATION CHEMISTRY REVIEWS (2017)

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(Pentamethylcyclopentadienyl)cobalt(III)-Catalyzed Direct Trifluoromethylthiolation of Arenes via C-H Activation

Xu-Ge Liu et al.

ADVANCED SYNTHESIS & CATALYSIS (2017)

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Iron(II)-catalyzed sulfur directed C(sp3)-H bond amination/C-S cross coupling reaction

Fang-Fang Duan et al.

CHEMICAL COMMUNICATIONS (2017)

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Cobalt-Catalyzed C-H Activation

Marc Moselage et al.

ACS CATALYSIS (2016)

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Cobalt-Catalyzed C-H Thiolation through Dehydrogenative Cross-Coupling

Tobias Gensch et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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A rhodium(I)-oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions

George Kleinhans et al.

CHEMICAL COMMUNICATIONS (2016)

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Aerobic copper-catalyzed decarboxylative thiolation

Minghao Li et al.

CHEMICAL COMMUNICATIONS (2016)

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Nickel-Catalyzed C-H Chalcogenation of Anilines

Thomas Mueller et al.

CHEMISTRY-A EUROPEAN JOURNAL (2016)

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Nickel-Catalyzed ortho-C-H Thiolation of N-Benzoyl α-Amino Acid Derivatives

Feng Gao et al.

JOURNAL OF ORGANIC CHEMISTRY (2016)

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Copper-Catalyzed 2,2,2-Trifluoroethylthiolation of Aryl Halides

Shouxiong Chen et al.

JOURNAL OF ORGANIC CHEMISTRY (2016)

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Rhodium-Catalyzed Regiodivergent Hydrothiolation of Allyl Amines and Imines

Jennifer L. Kennemur et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

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Sulfuration of the C(sp2)-H bond of enaminones: a protocol for the synthesis of thioether using elemental sulfur as a sulfurating reagent

Li-Fang Yang et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2016)

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Palladium-Catalyzed Regio- and Stereoselective Carbothiolation of Terminal Alkynes with Azolyl Sulfides

Masayuki Iwasaki et al.

ORGANIC LETTERS (2016)

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Palladium-Catalyzed Synthesis of 2,3-Disubstituted Benzothiophenes via the Annulation of Aryl Sulfides with Alkynes

Yoshihiro Masuya et al.

ORGANIC LETTERS (2016)

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Total Synthesis of K777: Successful Application of Transition-Metal-Catalyzed Alkyne Hydrothiolation toward the Modular Synthesis of a Potent Cysteine Protease Inhibitor

Erica R. Kiemele et al.

ORGANIC LETTERS (2016)

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Gold-Catalyzed Anti-Markovnikov Selective Hydrothiolation of Unactivated Alkenes

Taichi Tamai et al.

ORGANIC LETTERS (2016)

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Palladium-Catalyzed Stereoselective Formation of Substituted Allylic Thioethers and Sulfones

Jose Enrique Gomez et al.

ORGANIC LETTERS (2016)

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Copper-Catalyzed Oxysulfenylation of Enolates with Sodium Sulfinates: A Strategy To Construct Sulfenylated Cyclic Ethers

Yinglan Gao et al.

ORGANIC LETTERS (2016)

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Nature of the Copper-Oxide-Mediated C-S Cross-Coupling Reaction: Leaching of Catalytically Active Species from the Metal Oxide Surface

Yulia S. Panova et al.

ACS CATALYSIS (2016)

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Thiol-free route to diaryl sulfides by Cu catalyzed coupling of sodium thiosulfate with aryl halides

Najmeh Nowrouzi et al.

CHINESE JOURNAL OF CATALYSIS (2016)

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Z-Selective Hydrothiolation of Racemic 1,3-Disubstituted Allenes: An Atom-Economic Rhodium-Catalyzed Dynamic Kinetic Resolution

Adrian B. Pritzius et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

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Asymmetric Rhodium-Catalyzed Addition of Thiols to Allenes: Synthesis of Branched Allylic Thioethers and Sulfones

Adrian B. Pritzius et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

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A Reaction of Triazoles with Thioesters to Produce β-Sulfanyl Enamides by Insertion of an Enamine Moiety into the Sulfur-Carbonyl Bond

Tomoya Miura et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

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CO2-promoted oxidative cross-coupling reaction for C-S bond formation via masked strategy in an odourless way

Zongjun Qiao et al.

CHEMICAL COMMUNICATIONS (2015)

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A mild and facile synthesis of aryl and alkenyl sulfides via copper-catalyzed deborylthiolation of organoborons with thiosulfonates

Suguru Yoshida et al.

CHEMICAL COMMUNICATIONS (2015)

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Nickel-catalyzed thiolation of unactivated aryl C-H bonds: efficient access to diverse aryl sulfides

Sheng-Yi Yan et al.

CHEMICAL COMMUNICATIONS (2015)

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A Survey of the Role of Noncovalent Sulfur Interactions in Drug Design

Brett R. Beno et al.

JOURNAL OF MEDICINAL CHEMISTRY (2015)

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Method for the Synthesis of Phenothiazines via a Domino Iron-Catalyzed C-S/C-N Cross-Coupling Reaction

Weiye Hu et al.

JOURNAL OF ORGANIC CHEMISTRY (2015)

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Synthesis of Disubstituted Dithioethers: tert-Butoxide Promoted Elimination/Ring Opening of 1,3-Dithianes Followed by PalladiumCatalyzed C-S Bond Formation

Nissa Abidi et al.

JOURNAL OF ORGANIC CHEMISTRY (2015)

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Rhodium(III)-Catalyzed Directed ortho-C-H Bond Functionalization of Aromatic Ketazines via C-S and C-C Coupling

Jing Wen et al.

JOURNAL OF ORGANIC CHEMISTRY (2015)

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Fundamental Studies and Development of Nickel-Catalyzed Trifluoromethylthiolation of Aryl Chlorides: Active Catalytic Species and Key Roles of Ligand and Traceless MeCN Additive Revealed

Guoyin Yin et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

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NiSO4-catalyzed C-H activation/C-S cross-coupling of 1,2,3-triazole N-oxides with thiols

Jiayi Zhu et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2015)

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Activation of Aryl Thiocyanates Followed by Aryne Insertion: Access to 1,2-Thiobenzonitriles

Martin Pawliczek et al.

ORGANIC LETTERS (2015)

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Copper-Catalyzed Domino Synthesis of 2-Arylthiochromanones through Concomitant C-S Bond Formations Using Xanthate as Sulfur Source

Subramani Sangeetha et al.

ORGANIC LETTERS (2015)

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Rh-POP Pincer X-antphos Complexes for C-S and C-H Activation. Implications for Carbothiolation Catalysis

Peng Ren et al.

ORGANOMETALLICS (2015)

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Pd(II)-catalyzed selective sulfenylation of arene C-H bonds using N-arylthiobenzamides as thiolation reagent and oxidant

Xing-Song Zhang et al.

TETRAHEDRON (2015)

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A general and inexpensive protocol for the Cu-catalyzed C-S cross-coupling reaction between aryl halides and thiols

Anns Maria Thomas et al.

TETRAHEDRON LETTERS (2015)

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A novel and efficient zinc-catalyzed thioetherification of aryl halides

Amrutha P. Thankachan et al.

RSC ADVANCES (2015)

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2'-Cyanoethyl thioglycosides: effective nucleophiles for synthesis of (hetero)aryl thioglycosides under the catalysis of Cu

Xiaolong Yuan et al.

ORGANIC CHEMISTRY FRONTIERS (2015)

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The Palladium-Catalyzed Intermolecular C-H Chalcogenation of Arenes

Renhua Qiu et al.

JOURNAL OF ORGANIC CHEMISTRY (2015)

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Rhodium-Catalyzed Directed Sulfenylation of Arene C-H Bonds

Yaxi Yang et al.

CHEMISTRY-A EUROPEAN JOURNAL (2014)

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[(IPent) PdCl2(morpholine)]: A Readily Activated Precatalyst for Room-Temperature, Additive-Free Carbon-Sulfur Coupling

Jennifer L. Farmer et al.

CHEMISTRY-A EUROPEAN JOURNAL (2014)

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Data-Mining for Sulfur and Fluorine: An Evaluation of Pharmaceuticals To Reveal Opportunities for Drug Design and Discovery

Elizabeth A. Ilardi et al.

JOURNAL OF MEDICINAL CHEMISTRY (2014)

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Regioselective Hydrothiolation of Alkenes Bearing Heteroatoms with Thiols Catalyzed by Palladium Diacetate

Taichi Tamai et al.

JOURNAL OF ORGANIC CHEMISTRY (2014)

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Manganese-Catalyzed Cross-Coupling of Thiols with Aryl Iodides

Tsung-Jui Liu et al.

CHEMISTRY-AN ASIAN JOURNAL (2013)

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Synthesis of Aryl Thioethers through the N-Chlorosuccinimide-Promoted Cross-Coupling Reaction of Thiols with Grignard Reagents

Jun-Hao Cheng et al.

JOURNAL OF ORGANIC CHEMISTRY (2012)

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Nickel-Catalyzed Synthesis of Aryl Trifluoromethyl Sulfides at Room Temperature

Cheng-Pan Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

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Thiol-yne coupling: revisiting old concepts as a breakthrough for up-to-date applications

Alessandro Massi et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2012)

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Discovery of 1-[2-(2,4-Dimethylphenylsulfanyl)phenyl]piperazine (Lu AA21004): A Novel Multimodal Compound for the Treatment of Major Depressive Disorder

Benny Bang-Andersen et al.

JOURNAL OF MEDICINAL CHEMISTRY (2011)

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Formation of Carbon-Sulfur and Carbon-Selenium Bonds by Palladium-Catalyzed Decarboxylative Cross-Couplings of Hindered 2,6-Dialkoxybenzoic Acids

Jean-Michel Becht et al.

JOURNAL OF ORGANIC CHEMISTRY (2011)

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On the Role of Metal Contaminants in Catalyses with FeCl3

Stephen L. Buchwald et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

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Synthesis of Aryl Sulfides by Decarboxylative C-S Cross-Couplings

Zhongyu Duan et al.

CHEMISTRY-A EUROPEAN JOURNAL (2009)

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Cangrelor Attenuates Coated-Platelet Formation

Nicholas B. Norgard et al.

CLINICAL AND APPLIED THROMBOSIS-HEMOSTASIS (2009)

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Indium-Catalyzed C-S Cross-Coupling of Aryl Halides with Thiols

V. Prakash Reddy et al.

JOURNAL OF ORGANIC CHEMISTRY (2009)

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Iron-catalyzed S-arylation of thiols with aryl iodides

Arkaitz Correa et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

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Conformation-activity relationship on novel 4-pyridylmethylthio derivatives with antiangiogenic activity

Takahiro Honda et al.

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS (2008)

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Rhodium-catalyzed substitution reaction of aryl fluorides with disulfides:: p-orientation in the polyarylthiolation of polyfluorobenzenes

Mieko Arisawa et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)

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Cobalt-catalyzed aryl-sulfur bond formation

Ying-Chieh Wong et al.

ORGANIC LETTERS (2006)

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A highly regioselective cyanothiolation of alkynes via oxidative addition of thiocyanates to tetrakis(triphenylphosphine)palladium(0) catalyst

Ikuyo Kamiya et al.

ORGANOMETALLICS (2006)

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A general and long-lived catalyst for the palladium-catalyzed coupling of aryl halides with thiols

MA Fernández-Rodríguez et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2006)

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A general palladium-catalyzed coupling of aryl bromides/triflates and thiols

T Itoh et al.

ORGANIC LETTERS (2004)

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A mild, nonbasic synthesis of thioethers.: The copper-catalyzed coupling of boronic acids with N-thio(alkyl, aryl, heteroaryl)imides

C Savarin et al.

ORGANIC LETTERS (2002)

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