Journal
SYNTHESIS-STUTTGART
Volume 54, Issue 23, Pages 5139-5167Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/a-1914-1231
Keywords
thioethers; sulfides; homogeneous catalysis; coupling; hydrothiolation; C-H activation; decarbonylation
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Funding
- University of Tubingen
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This review provides a summary of the recent methods for the synthesis of thioethers using homogeneous metals as catalysts. Due to the widespread presence of the thioether moiety in pharmaceutical, agricultural, and material applications, it is essential to develop new, efficient synthesis methods. Recent efforts have focused on the use of non-precious metal catalysts and the development of new bond-forming processes.
This review summarizes the more recent methods (since 2015) for the synthesis of thioethers using homogeneous metals as catalysts. The thioether moiety can be found in numerous compounds for pharmaceutical, agricultural, or material applications and it is therefore important to develop new, efficient methods for their synthesis. The recent efforts in this field focus on the use of non-precious metal catalysts, as well as on the development of new bond-forming processes. 1 Introduction 2 Cross-Couplings 3 C-H Activation 4 Hydrothiolation 5 Carbothiolation 6 Miscellaneous 7 Conclusion
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