Journal
SYNLETT
Volume 33, Issue 16, Pages 1607-1618Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/a-1874-3463
Keywords
olefin metathesis polymerization; precision polymer; sequence control; acyclic diene metathesis polymerization; macrobicyclic olefin; ring-opening metathesis polymerization
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Funding
- National Natural Science Foundation of China [21971037]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
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This Account summarizes our research efforts and achievements in the field of olefin metathesis polymerization over the past decade, with a particular focus on acyclic diene metathesis (ADMET) polymerization and ring-opening metathesis polymerization (ROMP) strategies. The merits and limitations of these methods are also demonstrated, and our recently developed sequence-controlled ROMP strategy is highlighted.
Olefin metathesis polymerization has commanded great attention as a versatile method for preparing macromolecular materials with advanced architectures and functions in academia and industry. This Account summarizes our endeavors directed towards the preparation of various functional polymers by using olefin metathesis polymerization strategies in particular acyclic diene metathesis (ADMET) polymerization and ring-opening metathesis polymerization (ROMP), during the last ten years. In addition, the merits and limitations of ADMET polymerization and ROMP techniques are also demonstrated and compared. Notably, this Account highlights our recently developed sequence-controlled ROMP strategy for production of precision polymers in a regio-/stereoselective manner, the rollercoaster journey for the evolution of a macrobicyclic olefin system containing a sacrificial silyloxide bridge is described in detail.
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