4.4 Article

Photochemical Decarboxylative Formylation of Indoles with Aqueous Glyoxylic Acid

Related references

Note: Only part of the references are listed.
Article Chemistry, Physical

Selective decarboxylation of biobased fatty acids using a Ni-FSM-16 catalyst

Duangkamon Jiraroj et al.

Summary: A novel nickel catalyst supported on a folded sheet material (FSM) was synthesized and characterized, showing high reactivity and selectivity in decarboxylation reactions. Comparative investigation revealed that both the support and the metal of the catalyst were crucial for its superior catalytic performance.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Chemistry, Organic

Photo-on-Demand Synthesis of Vilsmeier Reagents with Chloroform and Their Applications to One-Pot Organic Syntheses

Fengying Liang et al.

Summary: The study demonstrates a novel method for the synthesis of Vilsmeier reagent directly from a CHCl3 solution under photo-irradiation with O-2 bubbling, avoiding the use of toxic and corrosive reagents. The generated Vilsmeier reagents can be isolated as crystalline solid products with high yields, allowing for analysis by X-ray crystallography. The unique advantage of using CHCl3 as both a reactant and a solvent makes this photo-on-demand synthesis available for one-pot syntheses of various organic compounds.

JOURNAL OF ORGANIC CHEMISTRY (2021)

Article Chemistry, Organic

Decarboxylative coupling of glyoxylic acid and its acetal derivatives: A unique C1 formylation synthon

Yunyu Xiang et al.

Summary: Glyoxylic acid and its acetal derivatives are low toxicity, easy to handle and store, highly stable, and readily available as formylation agents in decarboxylative cross-coupling reactions, showing great potential in various applications.

TETRAHEDRON (2021)

Article Chemistry, Multidisciplinary

Application of decarboxylation reactions for improvement of dielectric properties of a methacrylic polymer

Bao Li et al.

Summary: In this study, a method based on thermally induced decarboxylation was used to address the incompatibility of dielectric properties and developability of dielectric materials in aqueous developer solution. The synthesized polymer showed significant changes in dielectric properties and dissolubility due to thermally induced decarboxylation, as confirmed through various analyses. This approach offers a promising solution for improving the compatibility and performance of dielectric materials in photodefinable insulating applications.

RSC ADVANCES (2021)

Article Chemistry, Multidisciplinary

Recyclable and reusable n-Bu4NBF4/PEG-400/H2O system for electrochemical C-3 formylation of indoles with Me3N as a carbonyl source

Fei Ling et al.

Summary: This electrochemical methodology for the synthesis of 3-formylated indoles utilizes Me3N as a formylating reagent, eliminates the need for stoichiometric oxidants, metal catalysts, and activating agents, and uses a recyclable aqueous biphasic system as the reaction medium, expanding substrate scope and enhancing functional group tolerance. Late-stage functionalization and total/formal synthesis of drugs and natural products can be achieved through this sustainable and environmentally friendly approach.

GREEN CHEMISTRY (2021)

Review Chemistry, Multidisciplinary

Wonderful fusion of organofluorine chemistry and decarboxylation strategy

Pan Xiao et al.

Summary: Decarboxylation strategy is a powerful tool for the synthesis of fluorine-containing organic compounds, and can be achieved through the reaction of non-fluorinated carboxylic acids with fluorinating reagents, as well as the exploration and use of fluorine-containing carboxylic acids in decarboxylative transformations.

CHEMICAL SOCIETY REVIEWS (2021)

Article Chemistry, Applied

Photoredox-Catalyzed Redox-Neutral Minisci C-H Formylation of N-Heteroarenes

Jianyang Dong et al.

ADVANCED SYNTHESIS & CATALYSIS (2020)

Review Plant Sciences

Natural Products as Sources of New Drugs over the Nearly Four Decades from 01/1981 to 09/2019

David J. Newman et al.

JOURNAL OF NATURAL PRODUCTS (2020)

Article Multidisciplinary Sciences

Direct reversible decarboxylation from stable organic acids in dimethylformamide solution

Duanyang Kong et al.

SCIENCE (2020)

Review Chemistry, Multidisciplinary

α-Keto Acids: Acylating Agents in Organic Synthesis

Filipe Penteado et al.

CHEMICAL REVIEWS (2019)

Article Chemistry, Multidisciplinary

Recent advances of 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) in photocatalytic transformations

Tian-Yi Shang et al.

CHEMICAL COMMUNICATIONS (2019)

Article Chemistry, Multidisciplinary

Blue light photoredox-catalysed acetalation of alkynyl bromides

Xue-Li Lyu et al.

RSC ADVANCES (2019)

Article Chemistry, Multidisciplinary

Palladium-catalyzed hydroformylation of terminal arylacetylenes with glyoxylic acid

Yang Liu et al.

CHEMICAL COMMUNICATIONS (2018)

Review Chemistry, Multidisciplinary

Decarboxylative reactions with and without light - a comparison

Johanna Schwarz et al.

GREEN CHEMISTRY (2018)

Article Chemistry, Organic

Advances in Decarboxylative Oxidative Coupling Reaction

Tong Zhang et al.

JOURNAL OF ORGANIC CHEMISTRY (2018)

Article Chemistry, Organic

Selective nickel-catalyzed dehydrogenative-decarboxylative formylation of indoles with glyoxylic acid

Zhiping Yin et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2018)

Article Chemistry, Organic

Photoredox-Catalyzed Decarboxylative C-H Acylation of Heteroarenes

Wei Jia et al.

SYNLETT (2018)

Article Chemistry, Multidisciplinary

Chemo- and Regioselective Organo-Photoredox Catalyzed Hydroformylation of Styrenes via a Radical Pathway

He Huang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

An Ir-photoredox-catalyzed decarboxylative Michael addition of glyoxylic acid acetal as a formyl equivalent

Sheng Zhang et al.

CHEMICAL COMMUNICATIONS (2017)

Review Chemistry, Multidisciplinary

Recent Advances in Radical C-H Activation/Radical Cross-Coupling

Hong Yi et al.

CHEMICAL REVIEWS (2017)

Review Chemistry, Multidisciplinary

Decarboxylation as the Key Step in C-C Bond-Forming Reactions

Tuhin Patra et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

Article Chemistry, Organic

The ammonium-promoted formylation of indoles by DMSO and H2O

Haiyang Fei et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2013)

Article Chemistry, Multidisciplinary

nBu(4)NI-catalyzed C3-formylation of indoles with N-methylaniline

Lan-Tao Li et al.

CHEMICAL COMMUNICATIONS (2012)

Review Chemistry, Multidisciplinary

Decarboxylative coupling reactions: a modern strategy for C-C-bond formation

Nuria Rodriguez et al.

CHEMICAL SOCIETY REVIEWS (2011)

Article Chemistry, Multidisciplinary

Mild and Selective Ru-Catalyzed Formylation and Fe-Catalyzed Acylation of Free (N-H) Indoles Using Anilines as the Carbonyl Source

Wenliang Wu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Review Chemistry, Multidisciplinary

Corboxylic acids as substrates in homogeneous catalysts

Lukas J. Goossen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Review Chemistry, Organic

New methods for the preparation of aromatic aldehydes

W Kantlehner

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2003)