4.5 Article

Efficient catalytic oxidation of benzyl alcohol by tetrasubstituted cobalt phthalocyanine-MWCNTs composites

Journal

SOLID STATE SCIENCES
Volume 129, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.solidstatesciences.2022.106905

Keywords

Cobalt phthalocyanine; Multiwalled carbon nanotubes; Benzyl alcohol oxidation

Funding

  1. National Natural Science Foundation of China [21876015, 21703019]
  2. Natural Sci-ence Foundation of Jiangsu Higher Education Institutions [20KJA50007]
  3. Postgraduate Research & Practice Innovation Pro-gram of Jiangsu Province [SJCX21_1216]

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In this study, tetra-[alpha-(p-formyl) phenoxy] phthalocyanine cobalt (II)/multiwalled carbon nanotubes (CoPc/ MWCNTs) composites were prepared through the interaction between CoPc and MWCNTs. The structures of the composites were characterized using UV-vis spectroscopy, X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, and transmission electron microscopy. The catalytic efficiency of the composites in the oxidation reaction of benzyl alcohol was investigated under different reaction parameters.
In this paper, the tetra-[alpha-(p-formyl) phenoxy] phthalocyanine cobalt (II)/multiwalled carbon nanotubes (CoPc/ MWCNTs) composites were prepared through the it-it interactions between CoPc and MWCNTs. UV-vis spectroscopy, X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy and transmission electron microscopy were employed to characterize the structures of the prepared CoPc/MWCNTs composites. Its catalyzed oxidation properties were studied by carrying out the oxidation reaction of benzyl alcohol. The catalytic efficiency of these compounds under different reaction parameters such as catalyst dosage, temperature, time and various organic solvent was investigated.

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