Journal
SMALL
Volume 18, Issue 35, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.202201949
Keywords
amino-based carbon dots; chromium detection and adsorption; fluorescent aerogel; seawater desalination; solar thermoelectric generation
Categories
Funding
- National Natural Science Foundation of China [21607044, 31800494]
- Fundamental Research Funds for the Central Universities [2021MS102]
- Young Elite Scientists Sponsorship Program by CAST [2018QNRC001]
- Royal Society
- Open Research Fund of the School of Chemistry and Chemical Engineering, Henan Normal University [2020ZD01]
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The study involves the creation of a multifunctional CPC aerogel with efficient Cr(VI) adsorption capacity, meeting industrial water safety standards. It can be used for solar thermoelectric power generation and seawater desalination.
Heavy metal pollution has resulted in numerous environmental challenges. However, classic approaches, involving the use of solid adsorbents are subject to limitations, including the high energy consumption required for processing before and after use. Accordingly, strategies that facilitate the use of metal capture media that extends beyond waste remediation are attractive. Herein, a porous fluorescent aerogel (CPC aerogel) is constructed by immersing amino-based carbon dots (CDs-NH2) into a polyethyleneimine (PEI)/carboxymethylated cellulose (CMC) aerogel network for the simultaneous detection and adsorption of Cr(VI). Adsorption experiments confirm that the CMC/PEI containing CDs-NH2 aerogel (CPC aerogel) exhibits good Cr(VI) extraction capacity, and can reach a level that conforms with industrial water safety standards. In addition, the CPC aerogel can continuously detect and remove Cr(VI) at high flux. Following Cr(VI) absorption, the CPC aerogel may be vulcanized (MSx-CPC gel) and used for solar thermoelectric generation resulting in power generation. Additionally, the MSx-CPC gel can be used for solar steam generation and exhibits excellent evaporation rates of approximate to 1.31 kg m(-2) h(-1) under one sun irradiation. The results serve to underscore how materials designed for metal ion recognition and adsorption once exhausted can be exploited to provide materials for solar thermoelectric power generation and seawater desalination.
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